Synthesis of β‐Chloro‐α‐hydroxyphosphonates through Triethylamine‐Catalyzed Pudovik Reaction

2021 ◽  
Vol 6 (43) ◽  
pp. 11948-11950
Author(s):  
Huichuang Guo ◽  
Yuepeng Cao ◽  
Yulong Zhang ◽  
Qian Wu ◽  
Haibo Liu ◽  
...  
Keyword(s):  
Pudovik Reaction

The Pudovik Reaction

2004 ◽  
pp. 1
Author(s):  
T. Ooi ◽  
K. Maruoka
Keyword(s):  
Pudovik Reaction ◽  
The Pudovik Reaction

ChemInform Abstract: Rapid Access to New Thiazepinyl and Oxazepinyl Phosphonates Through a Green Pudovik Reaction.

ChemInform ◽  
2016 ◽  
Vol 47 (22) ◽  
Author(s):  
Debasmita Saha ◽  
Tanpreet Kaur ◽  
Neetu Singh ◽  
Udai P. Singh ◽  
Anuj Sharma
Keyword(s):  
Rapid Access ◽  
Pudovik Reaction

ChemInform Abstract: Synthesis of Novel Bis-Phosphonate Derivatives by Pudovik Reaction.

ChemInform ◽  
2009 ◽  
Vol 40 (6) ◽  
Author(s):  
B. Hari Babu ◽  
K. Srinivasulu ◽  
B. Venu Babu ◽  
R. Srinivas ◽  
C. Naga Raju
Keyword(s):  
Pudovik Reaction

scholarly journals The synthesis of α-aryl-α-aminophosphonates and α-aryl-α-aminophosphine oxides by the microwave-assisted Pudovik reaction

2017 ◽  
Vol 13 ◽  
pp. 76-86 ◽  
Author(s):  
Erika Bálint ◽  
Ádám Tajti ◽  
Anna Ádám ◽  
István Csontos ◽  
Konstantin Karaghiosoff ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Solvent Free ◽  
Primary Amines ◽  
Diphenylphosphine Oxide ◽  
Dimer Formation ◽  
X Ray ◽  
Microwave Assisted ◽  
Pudovik Reaction ◽  
Dialkyl Phosphites ◽  
Benzaldehyde Derivatives

A family of α-aryl-α-aminophosphonates and α-aryl-α-aminophosphine oxides was synthesized by the microwave-assisted solvent-free addition of dialkyl phosphites and diphenylphosphine oxide, respectively, to imines formed from benzaldehyde derivatives and primary amines. After optimization, the reactivity was mapped, and the fine mechanism was evaluated by DFT calculations. Two α-aminophosphonates were subjected to an X-ray study revealing a racemic dimer formation made through a N–H···O=P intermolecular hydrogen bridges pair.

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