Directed Vertical Diffusion of Photovoltaic Active Layer Components into Porous ZnO-Based Cathode Buffer Layers

Small ◽  
2018 ◽  
Vol 14 (15) ◽  
pp. 1704310 ◽  
Author(s):  
Jia-Jhen Kang ◽  
Tsung-Yu Yang ◽  
Yi-Kang Lan ◽  
Wei-Ru Wu ◽  
Chun-Jen Su ◽  
...  
2021 ◽  
Vol 95 (3) ◽  
pp. 30201
Author(s):  
Xi Guan ◽  
Yufei Wang ◽  
Shang Feng ◽  
Jidong Zhang ◽  
Qingqing Yang ◽  
...  

Organic solar cells (OSCs) have been fabricated using cathode buffer layers based on bathocuproine (BCP) and 4,4'-N,N'-dicarbazole-biphenyl (CBP). It is found that despite nearly same power conversion efficiencies, the bilayer of BCP/CBP shows increased thermal stability of device than the monolayer of BCP, mostly because upper CBP thin film stabilizes under BCP thin film. The mixed layer of BCP:CBP gives slightly decreased efficiency than BCP and BCP/CBP, mostly because the electron mobility of the OSC using BCP:CBP is decreased than those using BCP and BCP/CBP. However, the BCP:CBP increases thermal stability of device than BCP and BCP/CBP, ascribed to that the BCP and CBP effectively inhibit reciprocal tendencies of crystallizations in the mixed layer. Moreover, the BCP:CBP improves the light stability of device than the BCP and BCP/CBP, because the energy transfer from BCP to CBP in in the mixed layer effectively decelerates the photodegradation of BCP. We provide a facial method to improve the stabilities of cathode buffer layers against heat and light, beneficial to the commercial development of OSCs.


2012 ◽  
Vol 7 (10) ◽  
pp. 2305-2312 ◽  
Author(s):  
Yoshihiro Matano ◽  
Arihiro Saito ◽  
Yuto Suzuki ◽  
Tooru Miyajima ◽  
Seiji Akiyama ◽  
...  

2017 ◽  
Vol 5 (26) ◽  
pp. 6578-6587 ◽  
Author(s):  
Ashish Singh ◽  
Anamika Dey ◽  
Dipjyoti Das ◽  
Parameswar Krishnan Iyer

The combined influence of plasmonic metal nanoparticles and dual cathode buffer layers resulted in high-performance rrP3HT:PCBM based BHJ solar cells (PCE ∼5.65%).


2017 ◽  
Vol 5 (25) ◽  
pp. 13229-13229
Author(s):  
Jhao-lin Wu ◽  
Wen-Kuan Huang ◽  
Yu-Chia Chang ◽  
Bo-Chou Tsai ◽  
Yu-Cheng Hsiao ◽  
...  

Correction for ‘Simple mono-halogenated perylene diimides as non-fullerene electron transporting materials in inverted perovskite solar cells with ZnO nanoparticle cathode buffer layers’ by Jhao-lin Wu et al., J. Mater. Chem. A, 2017, DOI: 10.1039/c7ta02617j.


2010 ◽  
Vol 96 (26) ◽  
pp. 263506 ◽  
Author(s):  
Ching-Chun Chang ◽  
Chi-Feng Lin ◽  
Jian-Ming Chiou ◽  
Tzung-Han Ho ◽  
Yian Tai ◽  
...  

2013 ◽  
Vol 711 ◽  
pp. 39-44 ◽  
Author(s):  
Xiao Ran ◽  
Ng Tsz Wai ◽  
Xiu Juan Liang

Stability and efficiency have drawn much attention in research area. Buffer layers are inserted between the anode electrode (typically ITO) and active layer to obtain better performance. In this article development of different categories of materials as anode buffer layer and their possible mechanisms are reviewed.


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