scholarly journals Atomic‐level metal electrodeposition: synthetic strategies, applications, and catalytic mechanism in electrochemical energy conversion

2021 ◽  
Author(s):  
Yi Shi ◽  
Carmen Lee ◽  
Xianyi Tan ◽  
Lan Yang ◽  
Qiang Zhu ◽  
...  
2021 ◽  
Vol 7 (13) ◽  
pp. eabf3989
Author(s):  
Jiong Wang ◽  
Shuo Dou ◽  
Xin Wang

Heterogeneous molecular catalysts based on transition metal complexes have received increasing attention for their potential application in electrochemical energy conversion. The structural tuning of first and second coordination spheres of complexes provides versatile strategies for optimizing the activities of heterogeneous molecular catalysts and appropriate model systems for investigating the mechanism of structural variations on the activity. In this review, we first discuss the variation of first spheres by tuning ligated atoms; afterward, the structural tuning of second spheres by appending adjacent metal centers, pendant groups, electron withdrawing/donating, and conjugating moieties on the ligands is elaborated. Overall, these structural tuning resulted in different impacts on the geometric and electronic configurations of complexes, and the improved activity is achieved through tuning the stability of chemisorbed reactants and the redox behaviors of immobilized complexes.


JACS Au ◽  
2021 ◽  
Author(s):  
Florian D. Speck ◽  
Jae Hyung Kim ◽  
Geunsu Bae ◽  
Sang Hoon Joo ◽  
Karl J. J. Mayrhofer ◽  
...  

ChemInform ◽  
2014 ◽  
Vol 45 (51) ◽  
pp. no-no
Author(s):  
Shiyao Shan ◽  
Jin Luo ◽  
Jinfang Wu ◽  
Ning Kang ◽  
Wei Zhao ◽  
...  

2021 ◽  
pp. 2102801
Author(s):  
Yufei Zhao ◽  
Wen‐Jie Jiang ◽  
Jinqiang Zhang ◽  
Emma C. Lovell ◽  
Rose Amal ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document