Ultrahigh Sensitivity Wearable Sensors Enabled by Electrophoretic Deposition of Carbon Nanostructured Composites onto Everyday Fabrics

Wearable sensors are of increasing interest in emerging applications such as human-computer interaction, electronic skin, smart robotics, and rehabilitation monitoring. Here we report a novel garment-based sensor by integrating nanocomposite...

Optimizing Coating Thickness of Electrophoretic Deposition Overlay on Plasma Sprayed YSZ Coating Using Taguchi Method

In this study, nano sized yttria stabilized zirconia (YSZ) suspension in organic solution was deposited by electrophoretic deposition (EPD) method as a protective layer on substrate that was previously plasma sprayed thermal barrier coating (TBCs). In order to improve the performance of TBC from degradation by melt ingression of fuel impurities. Design of experiments (DOE) by Taguchi method was used to optimize the controlled variables of EPD process. A crack free YSZ overlay coating was carried out at different variables; applied voltage (20, 40, 60) V, deposition time (3, 5, 7) min and suspension concentration (5, 10, 15) g/l using DC current. Morphological appearance and cross section of the investigated coating specimen were done using optical and field emission scanning electron microscope. Optimizing process and analysis of variances (ANOVA) were performed by “Minitab 18” software. The results indicate that best condition of coating thickness can be obtained at 40V, 5min and 10g/l when applying signal-to-noise ratio “Larger is better”.

Effect of Ruthenium Oxide Content on the Electrochemical Characteristics of a Supercapacitor With a Carbon Black Electrode Formed by Electrophoretic Deposition

Controlling the ratio of capacitance and power of supercapacitors by changing the composition of the electrodes will allow to create optimal power systems for specific applications. For the formation of such electrodes, a method is required that combines the possibilities of creating a multicomponent composite with a high degree of uniformity of composition and morphology over the layer thickness. An example of such a method can be the eco-friendly method of electrophoretic deposition used in this work, which makes it possible to locally deposit a composite material from multicomponent suspensions at room temperature. We present an approach related to electrophoretic deposition from a suspension of composite material SuperC-RuO 2 , in which the ratio of the components can be changed to vary the proportion of electrochemical and electrical double layer storage. Nanocarbon, which has a large surface area, and ruthenium oxide with a significant electrochemical capacity, in combination, will allow combining high power and capacity in one device, and their ratio will determine the proportion of electrochemical and electrical double layer storage. In this work, approaches are investigated and recommendations are given for increasing the stability of suspensions, the effect of the composition of the suspension on the composition of composite electrodes and their capacitive and power characteristics is determined.

Versatile Strategy for Electrophoretic Deposition of Polyvinylidene Fluoride-Metal Oxide Nanocomposites

Polyvinylidene fluoride (PVDF) is an advanced functional polymer which exhibits excellent chemical and thermal stability, and good mechanical, piezoelectric and ferroelectic properties. This work opens a new strategy for the fabrication of nanocomposites, combining the functional properties of PVDF and advanced inorganic nanomaterials. Electrophoretic deposition (EPD) has been developed for the fabrication of films containing PVDF and nanoparticles of TiO2, MnO2 and NiFe2O4. An important finding was the feasibility of EPD of electrically neutral PVDF and inorganic nanoparticles using caffeic acid (CA) and catechol violet (CV) as co-dispersants. The experiments revealed strong adsorption of CA and CV on PVDF and inorganic nanoparticles, which involved different mechanisms and facilitated particle dispersion, charging and deposition. The analysis of the deposition yield data, chemical structure of the dispersants and the microstructure and composition of the films provided an insight into the adsorption and dispersion mechanisms and the influence of deposition conditions on the deposition rate, film microstructure and composition. PVDF films provided the corrosion protection of stainless steel. Overcoming the limitations of other techniques, this investigation demonstrates a conceptually new approach for the fabrication of PVDF-NiFe2O4 films, which showed superparamagnetic properties. The approach developed in this investigation offers versatile strategies for the EPD of advanced organic-inorganic nanocomposites.

Different colloidal particle formation process between conjugated polymer and unmodified C60 in preparation of suspension for electrophoretic deposition by reprecipitation method

Electrophoretic deposition provides material-efficient film formation on large area electrodes. In this study, it has been found that there is a significant difference in the colloidal particle formation process between a thiophene-based copolymer poly(3-octylthiophene- 2,5-diyl-co-3-decyloxythiophene-2,5-diyl) (POT-co-DOT) and C60 in preparation of suspension for electrophoretic deposition by reprecipitation method. This difference is attributed to the difference between low molecular weight materials with specific molecular weight and polymers with molecular weight distribution. The composition of POT-co-DOT:C60 composite film by electrophoretic deposition has also been estimated.