The Effect of Supplementary Pulverised Fuel Ash on Calcium Aluminate Phosphate Cement for Intermediate-Level Waste Encapsulation

Author(s):  
P. Swift ◽  
H. Kinoshita ◽  
N. C. Collier
Author(s):  
Robert J. Caldwell ◽  
Newton J. Bowmer ◽  
Edward J. Butcher ◽  
I. Hugh Godfrey

This paper presents the results of a laboratory-based programme to characterise full-scale, 500L cement-based wasteforms stored for over a decade. The wasteforms were prepared from inactive intermediate level waste (ILW) simulants, representing a range of ferric-based flocs produced during spent fuel reprocessing, using a blended ordinary Portland cement (OPC) / pulverised fuel ash (PFA) grout. The characterisation includes petrographic analysis, determination of moisture/density relationships, acid neutralisation capacity (ANC), and extraction analysis as a function of depth. The results of the study, conducted on full depth cores, indicate that the chosen matrix was well suited to the ferric floc waste that it was designed to contain. Carbonation and desiccation of the high water/solids wasteforms was limited to the near surface and the beneficial morphological and chemical characteristics of the matrix showed very little spatial variability.


Author(s):  
Y.G. Wang ◽  
H.Q. Ye ◽  
K.H. Kuo

A synthetic compound Ca4Al6SO16 (usually abbreviated as C4A3S) obtained by mixing CaO, A12O3 and CaSO4 powders and finally sintered at 1380°C is a cement with excellent hydraulicity and greatly expanding in application. It is hydralysed rapidly by water to form predominatly calcium aluminate hydrates and therefore unlikly to occur naturally, although structurally it may be regarded as an end member of the sodalite-hauynite series of naturally occuring minerals. C4A3S has a cubic structure with ao=9.19Å and space group . Fig.1 is the projection viewed down axis, in which there are two sets of 8C position in , namely CaI and CaII, occupied by the calcium atoms, respectively, and the ratio of occupations in these two sets of positions is about 3:1. This suggests that the calcium atoms can freely occupy these sites in various degrees and usually they almost locates on the CaI positions. A through-focus series of the lattice images were found in good agreement with the simulated ones. Each bright spot in the image taken at Scherzer defocus correspounds to a colunm of sulphur atom in the structural model (Fig.1).


2000 ◽  
Vol 49 (2) ◽  
pp. 209-214
Author(s):  
Minoru TAKEHIRO ◽  
Seishi GOTO ◽  
Koji IOKU ◽  
Hirotaka FUJIMORI

2016 ◽  
Vol 9 (2) ◽  
pp. 120-128
Author(s):  
Haspiadi Haspiadi ◽  
Kurniawaty Kurniawaty

Research of  the utilization solid waste of palm oil fuel ash from boiler as row materials  for manufacturing light concrete brick has been conducted. The main objective of this study is to investigate the potential use solid waste of palm oil fuel ash from palm oil mill boilers as row materials for manufacturing light concrete brick has recently attracted for an alternative environmentally sustainable application. In this study, light concrete brick made with various proportions of palm oil fuel ash from palm oil mill boilers and sand were fabricated and studied under laboratory scales. Percentage of palm oil fuel ash of 0% as a control,  10%, 20%, 30%, 40%, 50%, 60%, replacement  sand, wheras others materials such as Portland cement, lime, gypsum, foaming agent and aluminium with the numbers constant. The quality of light concreate brick   were applied followed by the compressive strength test, density and water absorption capacity. The study discovered that the compressive strength for all composition meet the recommended value to light structural of 6.89 MPa as prescribed in SNI 03-3449-2002. In the same manner density of light concrete brick for all proportion under the maximum density recommended value of 1400 Kg/m3 according to SNI 03-3449-2002. While water absorption capacity of increased by the increasing use of ashes. Therefore, palm oil fuel ash from boiler can be used as raw material for the light concrete brick which is  environmental friendly because using solid waste and also an alternative handling solid waste.ABSTRAKPenelitian pemanfaatan limbah padat abu cangkang dan serat kelapa sawit dari boiler sebagai bahan baku pembuatan bata beton ringan telah dilakukan. Tujuan dari penelitian ini adalah pemanfaatan limbah padat abu boiler berbahan bakar cangkang dan serat sebagai bahan pembuatan bata beton ringan sebagai salah satu alternatif pengelolaan lingkungan yang bekelanjutan. Dalam penelitian ini, bata beton ringan dibuat dengan berbagai komposisi abu boiler dan pasir yang diproduksi dalam  skala laboratorium. Persentase dari abu berturut-turut 0% sebagai kontrol, 10%, 20%, 30%, 40%, 50% dan 60% mensubtitusi pasir, sedangkan bahan lain yaitu semen, kapur, gypsum,  foaming  agent serta aluminium pasta dengan jumlah tetap. Mutu bata beton ringan yang diujikan adalah kuat tekan, bobot jenis dan daya serap air. Hasil penelitian menunjukkan bahwa kuat tekan untuk semua komposisi memenuhi batas minimum yang dipersyaratkan untuk stuktural ringan yaitu 6,89 MPa sesuai SNI 03-3449-2002. Demikian pula bobot jenis dari bata ringan yang dihasilkan masih dibawah dari batas maksimum yang direkomendasikan SNI 03-3449-2002 yaitu maksimal 1400 Kg/m3. Sedangkan daya serap air mengalami kenaikan dengan naiknya jumlah abu yang digunakan . Limbah padat abu boiler berbahan bakar cangkang dan serat sawit dapat dimanfaatkan sebagai bahan baku pembuatan bata beton ringan yang ramah lingkungan dengan memanfaatkan limbah dan menjadi salah satu alternatif pengelolaan limbah. Kata kunci :  Abu cangkang kelapa sawit,  bata beton ringan, bobot jenis,  daya serap air,  limbah,  kuat tekan


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