Interfering Optical Interactions: Phase Sensitive Absorption

1992 ◽  
pp. 241-254
Author(s):  
Ce Chen ◽  
Yi-Yian Yin ◽  
A. V. Smith ◽  
D. S. Elliott
Keyword(s):  
Phase Sensitive

Symmetry breaking in convergent-beam diffraction

1989 ◽  
Vol 47 ◽  
pp. 480-481
Author(s):  
D.J. Eaglesham
Keyword(s):  
Symmetry Breaking ◽  
Point Group ◽  
X Ray Diffraction ◽  
Multiple Diffraction ◽  
Space Groups ◽  
Atomic Displacements ◽  
Small Probe ◽  
Phase Sensitive ◽  
Convergent Beam

Convergent Beam Electron Diffraction is now almost routinely used in the determination of the point- and space-groups of crystalline samples. In addition to its small-probe capability, CBED is also postulated to be more sensitive than X-ray diffraction in determining crystal symmetries. Multiple diffraction is phase-sensitive, so that the distinction between centro- and non-centro-symmetric space groups should be trivial in CBED: in addition, the stronger scattering of electrons may give a general increase in sensitivity to small atomic displacements. However, the sensitivity of CBED symmetry to the crystal point group has rarely been quantified, and CBED is also subject to symmetry-breaking due to local strains and inhomogeneities. The purpose of this paper is to classify the various types of symmetry-breaking, present calculations of the sensitivity, and illustrate symmetry-breaking by surface strains.CBED symmetry determinations usually proceed by determining the diffraction group along various zone axes, and hence finding the point group. The diffraction group can be found using either the intensity distribution in the discs

Gradient-Enhanced Inverse-Detected NMR Techniquesfor Determination of 1H-15N Coupling Constants in 2,2-Dimethylpenta-3,4-dienal Derivatives

1997 ◽  
Vol 62 (11) ◽  
pp. 1747-1753 ◽  
Author(s):  
Radek Marek
Keyword(s):  
Double Bond ◽  
Chemical Shifts ◽  
Multiple Bond ◽  
Coupling Constants ◽  
Single Quantum ◽  
Nmr Techniques ◽  
Phase Sensitive ◽  
Heteronuclear Coupling

Determination of 15N chemical shifts and heteronuclear coupling constants of substituted 2,2-dimethylpenta-3,4-dienal hydrazones is presented. The chemical shifts were determined by gradient-enhanced inverse-detected NMR techniques and 1H-15N coupling constants were extracted from phase-sensitive gradient-enhanced single-quantum multiple bond correlation experiments. Stereospecific behaviour of the coupling constants 2J(1H,15N) and 1J(1H,13C) has been used to determine the configuration on a C=N double bond. The above-mentioned compounds exist predominantly as E isomers in deuteriochloroform.

The Interfacial Behaviour of Mono-, Di-, and Triphosphate of Inosine at the Charged Interface

1996 ◽  
Vol 61 (11) ◽  
pp. 1600-1608
Author(s):  
Mohamed E. Ahmed
Keyword(s):  
Divalent Metal ◽  
Divalent Metal Ions ◽  
Adsorption Parameters ◽  
Buffer Solutions ◽  
Ph Values ◽  
Adsorption Equilibria ◽  
Charged Interface ◽  
Interfacial Behaviour ◽  
Phase Sensitive ◽  
Adsorption Stage

The interfacial behaviour and adsorption equilibria of mono-, di-, and triphosphate of inosine (IMP, IDP, and ITP) were carried out in different buffer solutions by phase-sensitive ac voltammetry at HMDE. The characteristic properties and adsorption parameters of dilute and compact layers were evaluated from the obtained Frumkin isotherm at different pH values. The effect of some divalent metal ions on the adsorption stage and association of the investigated compounds has been studied.

A phase sensitive interferometer for the measurement of electron density in transient plasmas

1969 ◽  
Vol 2 (9) ◽  
pp. 776-778
Author(s):  
A E Dangor ◽  
J S Dolby ◽  
S J Fielding
Keyword(s):  
Electron Density ◽  
Phase Sensitive
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