Neural network aided diffractive metagratings for efficient beam splitting at terahertz frequencies

The merge of neural network with metasurfaces is a rising subject in photonics design, which offers an abstract bridge between the geometry of the subwavelength element and the optical response. The commonly involved optical response is the transmission or reflection spectrum, while here we focus on metasurfaces with superwavelength elements and predict multiple diffraction spectra in all the possible orders and orthogonal polarization modes given the geometry. This is achieved by parallel arrangement of several fully connected neural networks with shared input and diverse output diffraction spectra. As an application example, the model is used to find a metagrating as a 1:1 beam splitter in TE mode and 1:1:1 beam splitter in TM mode. The design is taken into fabrication and experimentally tested at 0.14 THz with highly consistent results to the prediction.

X-ray molecular orbital analysis. II. Application to diformohydrazide, (NHCHO)2

The molecular orbitals (MOs) of diformohydrazide have been determined from the electron density measured by X-ray diffraction. The experimental and refinement procedures are explained in detail and the validity of the obtained MOs is assessed from the crystallographic point of view. The X-ray structure factors were measured at 100 K by a four-circle diffractometer avoiding multiple diffraction, the effect of which on the structure factors is comparable to two-centre structure factors. There remained no significant peaks on the residual density map and the R factors reduced significantly. Among the 788 MO coefficients, 731 converged, of which 694 were statistically significant. The C—H and N—H bond distances are 1.032 (2) and 1.033 (3) Å, respectively. The electron densities of theoretical and experimental MOs and the differences between them are illustrated. The overall features of the electron density obtained by X-ray molecular orbital (XMO) analysis are in good agreement with the canonical orbitals calculated by the restricted Hartree Fock (RHF) method. The bonding-electron distribution around the middle of each bond is well represented and the relative phase relationships of the π orbitals are reflected clearly in the electron densities on the plane perpendicular to the molecular plane. However, differences are noticeable around the O atom on the molecular plane. The orbital energies obtained by XMO analysis are about 0.3 a.u. higher than the corresponding canonical orbitals, except for MO10 to MO14 which are about 0.7 a.u. higher. These exceptions are attributed to the N—H...O′′ intermolecular hydrogen bond, which is neglected in the MO models of the present study. The hydrogen bond is supported by significant electron densities at the saddle points between the H(N) and O′′ atoms in MO7, 8, 14 and 17, and by that of O′′-p extended over H(N) in MO21 and 22, while no peaks were found in MO10, 11, 13 and 15. The electron density of each MO clearly exhibits its role in the molecule. Consequently, the MOs obtained by XMO analysis give a fundamental quantum mechanical insight into the real properties of molecules.

Fourier-component engineering to control light diffraction beyond subwavelength limit

Resonant physical phenomena in planar photonic lattices, such as bound states in the continuum (BICs) and Fano resonances with 100% diffraction efficiency, have garnered significant scientific interest in recent years owing to their great ability to manipulate electromagnetic waves. In conventional diffraction theory, a subwavelength period is considered a prerequisite to achieving the highly efficient resonant physical phenomena. Indeed, most of the previous studies, that treat anomalous resonance effects, utilize quasiguided Bloch modes at the second stop bands open in the subwavelength region. Higher (beyond the second) stop bands open beyond the subwavelength limit have attracted little attention thus far. In principle, resonant diffraction phenomena are governed by the superposition of scattering processes, owing to higher Fourier harmonic components of periodic modulations in lattice parameters. But only some of Fourier components are dominant at band edges with Bragg conditions. Here, we present new principles of light diffraction, that enable identification of the dominant Fourier components causing multiple diffraction orders at the higher stopbands, and show that unwanted diffraction orders can be suppressed by engineering the dominant Fourier components. Based on the new diffraction principles, novel Fourier-component-engineered (FCE) metasurfaces are introduced and analyzed. It is demonstrated that these FCE metasurfaces with appropriately engineered spatial dielectric functions can exhibit BICs and highly efficient Fano resonances even beyond the subwavelength limit.

The Becoming of Online Healthcare through Entangled Power and Performativity: A posthumanist agential realist perspective

In this article we adopt Barad’s theory of agential realism to explore how power and performativity are simultaneously processual and ontologically entangled. We use the hyphenated term power-performativity to mobilize an exploration of how power is not an ‘outcome’ or ‘effect’ of, but an inseparable flow within, the processes of performativity through which the world is continuously becoming. This moves us beyond the traditional, anthropocentric take on the relationship between power and performativity which emphasizes human agency and linear cause-effect, toward an alternative understanding of organizational phenomena as always enacted through myriad intra-acting more-than-human actants. To empirically mobilize this approach, we explore power-performativity within online healthcare, enacted through personal online healthcare communities (POHCs). We explore multiple ‘diffraction gratings’ through which particular outcomes of online healthcare come to matter, while others are prevented from mattering. In doing so, we posit the suitability of Barad’s agential realism for further explorations of the dynamics of power and performativity in modes of organizing and organizational life and offer tools for how these may be done.

A Fast UTD-Based Method for the Analysis of Multiple Acoustic Diffraction over a Series of Obstacles with Arbitrary Modeling, Height and Spacing

A uniform theory of diffraction (UTD)-based method for analysis of the multiple diffraction of acoustic waves when considering a series of symmetric obstacles with arbitrary modeling, height and spacing is hereby presented. The method, which makes use of graph theory, funicular polygons and Fresnel ellipsoids, proposes a novel approach by which only the relevant obstacles and paths of the scenario under study are considered, therefore simultaneously providing fast and accurate prediction of sound attenuation. The obstacles can be modeled either as knife edges, wedges, wide barriers or cylinders, with some other polygonal diffracting elements, such as doubly inclined, T- or Y-shaped barriers, also considered. In view of the obtained results, this method shows good agreement with previously published formulations and measurements whilst offering better computational efficiency, thus allowing for the consideration of a large number of obstacles.