In the paper, we establish an evaluation system in the study of four aspects such as people, regulation, equipment and technology management, field management and engineering construction. We present an entropy weight multi-level fuzzy comprehensive evaluation model in power plant security on the basis of reliability identification. Firstly, it identifies the reliability of power plant security evaluation system. Secondly, it can meet the condition that the system is reliable. Then it obtains the indicator weight of all levels in the evaluation system by the entropy weight method. Finally, it carries out a comprehensive evaluation in power plant security by the multi-level fuzzy evaluation method.