133Cs NMR Studies of Cesium G.I.C.

Author(s):  
H. Estrade-Szwarckopf ◽  
J. Conard ◽  
P. Lauginie ◽  
J. Van der Klink ◽  
D. Guérard ◽  
...  
Keyword(s):  
1989 ◽  
Vol 34 (1-3) ◽  
pp. 577-582 ◽  
Author(s):  
I. Stang ◽  
K. Lüders ◽  
V. Geiser ◽  
H.-J. Güntherodt
Keyword(s):  

2001 ◽  
Vol 691 ◽  
Author(s):  
R.F. Marzke ◽  
G. S. Nolas ◽  
J. Gryko

ABSTRACTWe report 133Cs and 23Na spectra of Cs8NaxGe136 clathrates. Fully loaded Cs8Na16Ge136 shows only ionic signals from both Cs and Na nuclei. In contrast to the Cs8Na16Si136 clathrate, germanium Cs8Na16Ge136 clathrate shows no large Knight or paramagnetic shifts. However, when sodium is removed from Cs8Na16Ge136, the resulting Cs8Ge136 clathrate shows a very large shift in the 133Cs NMR spectrum.


1999 ◽  
Vol 96 (9/10) ◽  
pp. 1580-1584 ◽  
Author(s):  
I. Ségalas ◽  
S. Desjardins ◽  
H. Oulyadi ◽  
Y. Prigent ◽  
S. Tribouillard ◽  
...  

1994 ◽  
Vol 91 ◽  
pp. 697-703 ◽  
Author(s):  
B Gillet ◽  
BT Doan ◽  
C Verre-Sebrie ◽  
O Fedeli ◽  
JC Beloeil ◽  
...  

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-32-C8-35
Author(s):  
Y. Nakamura ◽  
M. Niibe ◽  
M. Shimoji
Keyword(s):  

1988 ◽  
Vol 49 (C8) ◽  
pp. C8-1713-C8-1714
Author(s):  
K. Le Dang ◽  
P. Veillet ◽  
H. Sakakima ◽  
R. Krishnan
Keyword(s):  

1990 ◽  
Vol 63 (03) ◽  
pp. 499-504 ◽  
Author(s):  
A Electricwala ◽  
L Irons ◽  
R Wait ◽  
R J G Carr ◽  
R J Ling ◽  
...  

SummaryPhysico-chemical properties of recombinant desulphatohirudin expressed in yeast (CIBA GEIGY code No. CGP 39393) were reinvestigated. As previously reported for natural hirudin, the recombinant molecule exhibited abnormal behaviour by gel filtration with an apparent molecular weight greater than that based on the primary structure. However, molecular weight estimation by SDS gel electrophoresis, FAB-mass spectrometry and Photon Correlation Spectroscopy were in agreement with the theoretical molecular weight, with little suggestion of dimer or aggregate formation. Circular dichroism studies of the recombinant molecule show similar spectra at different pH values but are markedly different from that reported by Konno et al. (13) for a natural hirudin-variant. Our CD studies indicate the presence of about 60% beta sheet and the absence of alpha helix in the secondary structure of recombinant hirudin, in agreement with the conformation determined by NMR studies (17)


2003 ◽  
Vol 772 ◽  
Author(s):  
M. Schmid ◽  
C. Goze-Bac ◽  
M. Mehring ◽  
S. Roth ◽  
P. Bernier

AbstractLithium intercalted carbon nanotubes have attracted considerable interest as perspective components for energy storage devices. We performed 13C Nuclear Magnetic Resonance spin lattice relaxation measurements in a temperature range from 4 K up to 300 on alkali intercalated Single Walled Carbon Nanotubes in order to investigate the modifications of the electronic properties. The density of states at the Fermi level were determined for pristine, lithium and cesium intercalated carbon nanotubes and are discussed in terms of intercalation and charge transfer effects.


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