Cyano Radical

2015 ◽  
pp. 589-589
Keyword(s):  
Cyano Radical

A chemical dynamics, kinetics, and theoretical study on the reaction of the cyano radical (CN; X2Σ+) with phenylacetylene (C6H5CCH; X1A1)

2010 ◽  
Vol 12 (31) ◽  
pp. 8737 ◽  
Author(s):  
Chris J. Bennett ◽  
Sébastien B. Morales ◽  
Sébastien D. Le Picard ◽  
André Canosa ◽  
Ian R. Sims ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Chemical Dynamics ◽  
Cyano Radical

Anharmonic effect of the reactions related to cyano radical as reactant in fuel combustion mechanism

2019 ◽  
Vol 516 ◽  
pp. 38-47 ◽  
Author(s):  
Rui Zhao ◽  
Duo Gao ◽  
Xinxiang Pan ◽  
Liguo Song ◽  
Hongjing Yu ◽  
...  
Keyword(s):  
Fuel Combustion ◽  
Combustion Mechanism ◽  
Anharmonic Effect ◽  
Cyano Radical

scholarly journals Cyanogen, cyanoacetylene, and acetonitrile in comet 67P and their relation to the cyano radical

2021 ◽  
Author(s):  
N. Hänni ◽  
K. Altwegg ◽  
H. Balsiger ◽  
M. Combi ◽  
S. A. Fuselier ◽  
...  
Keyword(s):  
Cyano Radical ◽  
Comet 67P

scholarly journals A Computational Study of the Reaction Cyanoacetylene and Cyano Radical Leading to 2-Butynedinitrile and Hydrogen Radical

2020 ◽  
pp. 707-716
Author(s):  
Emília Valença Ferreira de Aragão ◽  
Noelia Faginas-Lago ◽  
Marzio Rosi ◽  
Luca Mancini ◽  
Nadia Balucani ◽  
...  
Keyword(s):  
Computational Study ◽  
Hydrogen Radical ◽  
Cyano Radical

scholarly journals Crossed Molecular Beam Experiments of Radical-Neutral Reactions Relevant to the Formation of Hydrogen Deficient Molecules in Extraterrestrial Environments

2000 ◽  
Vol 197 ◽  
pp. 251-264 ◽  
Author(s):  
R. I. Kaiser ◽  
N. Balucani ◽  
O. Asvany ◽  
Y. T. Lee
Keyword(s):  
Laboratory Experiments ◽  
Molecular Beam ◽  
Carbon Clusters ◽  
Reaction Products ◽  
Chemical Reaction Dynamics ◽  
Cyano Radical ◽  
First Time ◽  
Beam Technique ◽  
Collision Complexes ◽  
Crossed Molecular Beam

During the last 5 years, laboratory experiments relevant to the formation of carbon-bearing molecules in extraterrestrial environments have been performed employing the crossed molecular beam technique and a high intensity source of ground state atomic carbon, C(3Pj). These investigations unraveled for the first time detailed information on the chemical reaction dynamics, involved collision complexes and intermediates, and – most important – reaction products of neutral-neutral reactions. Here, we extend these studies even further, and report on very recent crossed beam experiments of cyano radical, CN(2Σ+), reactions with unsaturated hydrocarbons to form nitriles in extraterrestrial environments and Saturn's moon Titan. Further, preliminary results on reactions of small carbon clusters and with acetylene, ethylene, and methylacetylene to synthesize hydrogen-deficient carbon-bearing molecules are presented.

Observations regarding .delta.- and .epsilon.-cyano radical cyclizations

1985 ◽  
Vol 50 (25) ◽  
pp. 5409-5410 ◽  
Author(s):  
Balan Chenera ◽  
Che Ping Chuang ◽  
David J. Hart ◽  
Leh Yeh Hsu
Keyword(s):  
Radical Cyclizations ◽  
Cyano Radical

scholarly journals Selective Phthalimido-N-oxyl (PINO)-Catalyzed C–H Cyanation of Adamantane Derivatives

Synlett ◽  
2018 ◽  
Vol 30 (04) ◽  
pp. 493-498 ◽  
Author(s):  
Jan-Philipp Berndt ◽  
Frederik Erb ◽  
Lukas Ochmann ◽  
Jaqueline Beppler ◽  
Peter Schreiner
Keyword(s):  
New Method ◽  
Adamantane Derivatives ◽  
Mechanistic Studies ◽  
Cyano Radical

We present a new method for the selective C(sp3)–H cyanation of adamantane derivatives with PINO as the hydrogen abstracting reagent. A cyano radical is thereby transferred from p -toluenesulfonyl cyanide, allowing the cyanation of adamantane derivatives in up to 71% yield. The protocol presents a novel way to orthogonally functionalized adamantanes that are otherwise difficult to prepare. Mechanistic studies support the hypothesis of a radical pathway.

Kinetics study of the CN + CH4 hydrogen abstraction reaction based on a new ab initio analytical full-dimensional potential energy surface

2017 ◽  
Vol 19 (29) ◽  
pp. 19341-19351 ◽  
Author(s):  
Joaquin Espinosa-Garcia ◽  
Cipriano Rangel ◽  
Yury V. Suleimanov
Keyword(s):  
Potential Energy ◽  
Potential Energy Surface ◽  
Ab Initio ◽  
Gas Phase ◽  
Energy Surface ◽  
Hydrogen Abstraction ◽  
Kinetics Study ◽  
Abstraction Reaction ◽  
Cyano Radical ◽  
Hydrogen Abstraction Reaction

We have developed an analytical full-dimensional potential energy surface, named PES-2017, for the gas-phase hydrogen abstraction reaction between the cyano radical and methane.

Sign in / Sign up

Export Citation Format

Share Document