Novel Approaches to Protein Structural Analyses Using Combinations of Optical Spectroscopic Methods (Electronic and Vibrational Circular Dichroism and Ftir Studies)

Author(s):  
P. Pancoska ◽  
V. Janota ◽  
T. A. Keiderling
2021 ◽  
Vol 9 ◽  
Author(s):  
Chao Yuan ◽  
Yuhua Guo ◽  
Ke Wang ◽  
Zhunian Wang ◽  
Longfei Li ◽  
...  

Two known azaphilone derivatives, 4,6-dimethylcurvulinic acid (1) and austdiol (2), and their novel heterotrimer, muyophilone A (3), were isolated and identified from an endophytic fungus, Muyocopron laterale 0307-2. Their structures and stereochemistry were established by extensive spectroscopic analyses including HRMS, NMR spectroscopy, electronic circular dichroism (ECD) and vibrational circular dichroism (VCD) spectroscopic methods, as well as single crystal X-ray diffraction. In the structure of 3, two compound 2-derived azaphilone units were connected through an unprecedented five-membered carbon bridge which was proposed to be originated from compound 1. Compound 3 represents the first example of azaphilone heterotrimers.


ChemInform ◽  
1988 ◽  
Vol 19 (28) ◽  
Author(s):  
K. J. JALKANEN ◽  
P. J. STEPHENS ◽  
R. D. AMOS ◽  
N. C. HANDY

Heterocycles ◽  
2012 ◽  
Vol 85 (8) ◽  
pp. 1961 ◽  
Author(s):  
Pedro Joseph-Nathan ◽  
Marcelo A. Muñoz ◽  
Carlos Areche ◽  
Juana Rovirosa ◽  
Aurelio San Martín ◽  
...  

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