Selective Oxidation of Light Alkanes

1998 ◽  
pp. 125-156 ◽  
Author(s):  
G. J. Hutchings
Keyword(s):  
Selective Oxidation ◽  
Light Alkanes

Novel Selective Oxidation of Light Alkanes Using Carbon Dioxide. Oxidized Diamond as a Novel Catalytic Medium

2003 ◽  
Vol 32 (9) ◽  
pp. 866-867 ◽  
Author(s):  
Kiyoharu Nakagawa ◽  
Kimito Okumura ◽  
Takahiro Shimamura ◽  
Na-oki Ikenaga ◽  
Toshimitsu Suzuki ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Selective Oxidation ◽  
Light Alkanes ◽  
Catalytic Medium ◽  
Oxidized Diamond

Development and Application of Oxygen Permeable Membrane in Selective Oxidation of Light Alkanes

2005 ◽  
Vol 35 (1-2) ◽  
pp. 155-167 ◽  
Author(s):  
Weishen Yang ◽  
Haihui Wang ◽  
Xuefeng Zhu ◽  
Liwu Lin
Keyword(s):  
Selective Oxidation ◽  
Permeable Membrane ◽  
Light Alkanes ◽  
Oxygen Permeable Membrane

DEVELOPING SELECTIVE OXIDATION CATALYSTS OF LIGHT ALKANES: FROM FUNDAMENTAL UNDERSTANDING TO RATIONAL DESIGN

2007 ◽  
Vol 14 (04) ◽  
pp. 645-656 ◽  
Author(s):  
GANG FU ◽  
XIAODONG YI ◽  
CHUANJING HUANG ◽  
XIN XU ◽  
WEIZHENG WENG ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Rational Design ◽  
Acid Sites ◽  
Active Components ◽  
Active Centers ◽  
Light Alkanes ◽  
Key Issues ◽  
Spatial Isolation ◽  
Oxygen Anions ◽  
The Stability

Selective oxidation of light alkanes remains to be a great challenge for the wider use of alkanes as feedstocks. To achieve high activity and at the same time high selectivity, some key issues have to be addressed: (1) the stability of the desired products with respect to the reactants; (2) the roles of the active components in the catalysts, the structure and the functionality of the active centers; (3) the reducibility of the metal cations, the Lewis acid sites and their synergic effects with the basic sites of the lattice oxygen anions; (4) spatial isolation of the active centers; and (5) the mechanisms for the formation and transformation of the intermediates and their kinetic controls. In this contribution, we took selective oxidation of propane to acrolein as our target reaction, and reviewed mainly our own work, trying to provide some thinking and answers to these five questions.

ChemInform Abstract: Selective Oxidation of Light Alkanes

ChemInform ◽  
2010 ◽  
Vol 29 (38) ◽  
pp. no-no
Author(s):  
G. J. HUTCHINGS
Keyword(s):  
Selective Oxidation ◽  
Light Alkanes
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