Kinetics of aquation of cis- and trans-chloro-nitrobis(ethylenediamine) cobalt(III) ion in aqueous mixtures of ethylene carbonate and propylene carbonate

1996 ◽  
Vol 21 (2) ◽  
pp. 184-186 ◽  
Author(s):  
Ol'ga Grančičová
Keyword(s):  
Propylene Carbonate ◽  
Ethylene Carbonate ◽  
Aqueous Mixtures ◽  
Cis And Trans ◽  
Kinetics Of

Transfer Thermodynamic Functions ∆Gt0, ∆Ht0 and T∆St0 of cis- and trans-[CoCl2(en)2]+ Isomers in Aqueous Mixtures of Methanol, tert-Butyl Alcohol and Acetonitrile

2000 ◽  
Vol 65 (9) ◽  
pp. 1455-1463
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Enthalpy Of Solution ◽  
Transfer Functions ◽  
Partial Molar Volumes ◽  
Butyl Alcohol ◽  
Aqueous Mixtures ◽  
Aqueous Methanol ◽  
Solvent Interactions ◽  
Tert Butyl Alcohol ◽  
Surface Charge Distribution ◽  
Cis And Trans

The solubility, partial molar volume and standard integral molar enthalpy of solution of cis- and trans-[CoCl2(en)2]Cl in water, aqueous methanol, aqueous tert-butyl alcohol and aqueous acetonitrile are reported. The transfer functions ∆Gt0, ∆Ht0 and T∆St0 as well as partial molar volumes are used to obtain information on the solute-solvent interactions. Results obtained are discussed in terms of differences in the surface charge distribution in isomeric coordination species.

Activity Coefficients of NaCl in Aqueous Mixtures with High Relative Permittivity Cosolvent: Ethylene Carbonate + Water at 298.15 K

2010 ◽  
Vol 55 (9) ◽  
pp. 3349-3355 ◽  
Author(s):  
Felipe Hernández-Luis ◽  
Raquel Rodríguez-Raposo ◽  
Héctor R. Galleguillos ◽  
Jaime W. Morales
Keyword(s):  
Activity Coefficients ◽  
Relative Permittivity ◽  
Ethylene Carbonate ◽  
Aqueous Mixtures ◽  
Carbonate Water ◽  
High Relative Permittivity

Kinetics of the Isomerization of 1-Decene to cis- and trans-2-Decene

1995 ◽  
Vol 60 (13) ◽  
pp. 4255-4257 ◽  
Author(s):  
Mario L. Aimar ◽  
Rita H. de Rossi
Keyword(s):  
Cis And Trans ◽  
Kinetics Of
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