ChemInform Abstract: Isolation, Characterization, and Kinetics of Formation of the cis and trans Isomers of Bis(acetonitrile)dichloroplatinum(II).

ChemInform ◽  
1990 ◽  
Vol 21 (14) ◽  
Author(s):  
F. P. FANIZZI ◽  
F. P. INTINI ◽  
L. MARESCA ◽  
G. NATILE
1992 ◽  
Vol 47 (10) ◽  
pp. 1431-1437 ◽  
Author(s):  
M. J. Melo ◽  
Fernando Pina ◽  
António L. Maçanita ◽  
Eurico C. Melo ◽  
Christiane Herrmann ◽  
...  

The photodegradation of 2-(2-Furyl)-benzimidazole (Fuberidazole 1) has been reinvestigated employing advanced HPLC—UV/VIS technique and fluorescence emission and excitation spectroscopy in methanol at natural pH, in acidic medium and in aqueous solutions at pH 7 and 3, and four main products benzimidazole-2-carboxylic acid 3, its methyl ester 2, 1-methoxy benzimidazole 5, methyl 4-oxo-2-benzimidazole crotonate 7 (cis and trans isomers) besides benzimidazole 4 and 2,2′-bibenzimidazole 6 and other side products have been isolated and characterized. The kinetics of the photodegradation process was followed independently by HPLC—UV and fluorescence emission showing a significant similarity of the curve habit; this allows to monitor a photodegradation at very low concentrations (5·10-5-5·10-6Μ). The quantum yield of disappearance of Fuberidazole has been determined.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4539
Author(s):  
Nguyen Minh Thuy ◽  
Vo Minh ◽  
Tran Ben ◽  
My Tuyen Thi Nguyen ◽  
Ho Ha ◽  
...  

Butterfly pea flower have great sensory attraction, but they have not yet been used widely in Vietnam. Extracts of butterfly pea flowers can be used conveniently as a natural blue colorant for food products. In this study, the identification of anthocyanin compounds in butterfly pea flowers was performed by UPLC coupled with a UV and Mass spectrometer instrument. Positive and negative ion electrospray MS/MS chromatograms and spectra of the anthocyanin compounds were determined. By analyzing the chromatograms and spectra for each ion, five anthocyanins were identified in the butterfly pea flower extract; these were delphinidin-3-(6”‐p-coumaroyl)-rutinoside, cyanidin 3-(6”-p-coumaroyl)-rutinoside, delphinidin-3-(p-coumaroyl) glucose in both cis- and trans- isomers, cyanidin-3-(p-coumaroyl-glucoside) and delphinidin-3-pyranoside. Additionally, based on their intensity, it was determined that cyanidin-3-(p-coumaroyl-glucoside) was the most abundant anthocyanin, followed by cyanidin 3-(6”-p-coumaroyl)-rutinoside, delphinidin-3-(p-coumaroyl-glucoside), delphinidin-3-(6”-p-coumaroyl)-rutinoside and delphinidin-3-pyranoside. In this study, cyanidin derivatives were discovered in butterfly pea flower extract, where these compounds had not been detected in previous studies.


2020 ◽  
Vol 153 (24) ◽  
pp. 244308
Author(s):  
Ali Abou Taka ◽  
Mark C. Babin ◽  
Xianghai Sheng ◽  
Jessalyn A. DeVine ◽  
Daniel M. Neumark ◽  
...  

1957 ◽  
Vol 35 (8) ◽  
pp. 757-760 ◽  
Author(s):  
K. K. Carroll

The malonic ester synthesis of nervonic acid (tetracos-15-enoic acid) has been modified so that the product consists of pure cis rather than a mixture of cis and trans isomers. The modified synthesis has been used for the preparation of C14-labelled erucic and nervonic acids.


2002 ◽  
Vol 67 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Zenon Łotowski ◽  
Jacek W. Morzycki ◽  
Izabella S. Niewczas ◽  
Marta Zdanowicz

Treatment of 16α-bromo-17-oxosteroids 1 and 2 with gaseous ammonia and successive air-oxidation afforded the cis and trans isomers of D-linked bis-steroid pyrazines. Analogous reaction of 1α-bromo-4-nor-5α-cholestan-2-one (3) led to unexpected hydrolysis products.


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