Monitoring of total aromatic hydrocarbons in a benzine stream from catalytic reforming

1967 ◽  
Vol 7 (6) ◽  
pp. 620-621
Author(s):  
V. S. Pavlova ◽  
Yu. N. Gusev ◽  
V. N. Noskov ◽  
Yu. K. Lebedev
1967 ◽  
Vol 7 (2) ◽  
pp. 121-128 ◽  
Author(s):  
G MASLYANSKII ◽  
A POTAPOVA ◽  
V SKORNYAKOVA

2018 ◽  
Vol 95 (9) ◽  
pp. 1201-1211
Author(s):  
Shelby Amsley-Benzie ◽  
Swapnil Fegade ◽  
Brian Tande ◽  
Alena Kubátová ◽  
Evguenii Kozliak ◽  
...  

2021 ◽  
pp. 860-878
Author(s):  
O. Sych ◽  
A. Korniienko ◽  
N. Yevtushenko

The main types of petroleum components that are used in the manufacture of mixed motor gasolines are considered. For the manufacture of mixed motor gasolines, a low-octane base is used, to which high-octane components are added. In many cases, reformate (catalytic reforming gasoline) and isopentane (isopentane fraction) are used as high-octane components of mixed motor gasolines. Straight-run gasoline and stable gasoline are often used as the low-octane gasoline base of blended automobile gasolines. Reformate is a liquid mixture of aromatic and saturated hydrocarbons used as a high-octane component of automobile (aviation) gasolines and raw materials in the production of aromatic hydrocarbons (arenas). The reformate is obtained by catalytic reforming of straight-run gasoline fractions. Isopentane (2-methylbutane (CH3)2CHCH2CH3) is a colorless, flammable liquid. The technical product is a mixture of isomeric pentanes and boils within 24 - 34°C. The isopentane fraction can be isolated from gas gasoline, from gasoline direct distillation of oil and gasoline catalytic cracking. Straight-run gasoline (nefras) is obtained from the processing of crude oil or gas condensate, oil shale or coal, natural gas or oil and gas. Straight run gasoline contains light gasoline fractions of direct distillation of oil with a boiling range of 35 - 180°C. Gas gasoline (gas stable gasoline) is obtained from natural and petroleum gases containing vapors of gasoline hydrocarbons. To separate them, the gases are compressed and cooled (compression method) or absorbed with oil or activated carbon. Gas gasoline is similar in chemical composition to straight-run gasoline, but contains lighter hydrocarbon fractions. The article discusses the results of a study of the listed petroleum components of mixed gasoline by gas-liquid chromatography. This method allows you to establish the qualitative and quantitative composition of mixed motor gasolines and their components. It is shown that from readily available petroleum components (isopentane fraction, aromatic hydrocarbons and gas stable gasoline) without the use of sophisticated technological equipment, a gasoline mixture with high detonation resistance, which is falsified automobile gasoline, can be obtained by mixing method. When mixed in certain proportions of reformate, isopentane fraction and gas stable gasoline, it is possible to obtain marketable gasoline that will meet the requirements of regulatory documents for gasoline. The considered technology allows, when mixing commodity gasolines A-92 (A-95) with reformate, isopentane fraction and gasoline gas stable in the calculated proportions, to improve the operational characteristics (detonation resistance) of the obtained gasoline mixture or to increase the volume of the obtained gasoline mixture without improving its performance.


2019 ◽  
Vol 19 (6) ◽  
pp. 465-473
Author(s):  
R. Z. Zainullin ◽  
A. N. Zagoruiko ◽  
K. F. Koledina ◽  
I. M. Gubaidullin ◽  
R. I. Faskhutdinova

The study is devoted to multicriteria optimization of the operation of the reactor unit intended for reforming of oil fractions. The optimization is based on the earlier developed mathematical model, which can take into account changes in the temperature and molar consumption of the reaction mixture during chemical transformations, the composition of the feedstock being processed, and the circulation quality and ratio of the hydrogen-containing gas. The following criteria are used in such optimization: octane number, yield of the target product (reformate), content of the sum of aromatic hydrocarbons, and content of benzene. The optimization was implemented using Pareto approximation with the genetic algorithm. Temperatures at the reactor inlets served as the control parameters. As a result of optimization, the sum content of aromatic hydrocarbons decreases from 56 to 45 wt.%, and the octane number measured by the research method (RON) decreases from 92.7 to 90.7 points. The three-criteria optimization is also considered; it provides a decrease in the benzene content from 4 to 3.08 wt.% with a decrease in RON from 92.7 to 91.8 points. In both cases, the decrease in the octane number is admissible, taking into account the fulfilled requirements to the limiting content of benzene and aromatic hydrocarbons in the reformate.


1972 ◽  
Vol 8 (8) ◽  
pp. 569-572
Author(s):  
A. P. Fedorov ◽  
G. N. Maslyanskii ◽  
V. V. Shipikin ◽  
N. P. Mel'nikova ◽  
E. A. Shkuratova ◽  
...  

2020 ◽  
pp. 45-50
Author(s):  
R.G. Ibrahimov ◽  
◽  
Kh. I. Abad-zade ◽  
R.O. Mejidov ◽  
◽  
...  

Currently, in the atmospheric installation in the cutting of benzene fraction ibp -180 оС to the ibp -85 and 85–180 оС, due to the indefinite rectification of benzole and in the catalytic reforming of benzole-forming hydrocarbons (hexamethylene, hexane, metylcyclopentane) transfer to the fractions 85–180 оС. Therefore, the temperature of initial boiling point of reforming raw is increased up to 95 оС, which significantly decreases the amount of reforming crude. To that end, the paper offers to conduct precise benzene rectification of ibp -180 оС to the ibp -85 and 85–180 оС, and then increase octane number of the fraction ibp -85 adding less toxic additive, to carry out the reforming process in mild regime and perform compounding of the fraction ibp -85 after octane-increasing additive and reformate. In addition, the composition of aromatic hydrocarbons and benzole is dramatically decreased compared to reformat obtained on reforming installation at Oil Refinery named after Heydar Aliyev.


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