Effect of diffusion-diaphragm surface conditions on determination of diffusion coefficient and penetration factor of hydrogen into iron and ferrous alloys

1976 ◽  
Vol 10 (5) ◽  
pp. 522-524
Author(s):  
V. I. Salii ◽  
R. A. Ryabov
1986 ◽  
pp. 445-450
Author(s):  
Chao Jinlan ◽  
Zhou Zuoxiang ◽  
Guo Zhunhuan ◽  
Wang Ruimin ◽  
Wan Genshi

1993 ◽  
Author(s):  
M. de Murcia ◽  
D. Gasquet ◽  
E. Richard ◽  
P. Wolff ◽  
J. Zimmermann ◽  
...  

The Analyst ◽  
1950 ◽  
Vol 75 (894) ◽  
pp. 481 ◽  
Author(s):  
M. H. Jenkins ◽  
J. A. V. Webb
Keyword(s):  

1996 ◽  
Vol 05 (01) ◽  
pp. 3-11 ◽  
Author(s):  
GÜLHAYAT NASÜN-SAYGILI ◽  
HASANCAN OKUTAN

1997 ◽  
Vol 496 ◽  
Author(s):  
M. Inaba ◽  
S. Nohmi ◽  
A. Funabiki ◽  
T. Abe ◽  
Z. Ogumi

ABSTRACTThe electrochemical permeation method was applied to the determination of the diffusion coefficient of Li+ion (DLi+) in a glassy carbon (GC) plate. The cell was composed of two compartments, which were separated by the GC plate. Li+ions were inserted electrochemically from one face, and extracted from the other. The flux of the permeated Li+ions was monitored as an oxidation current at the latter face. The diffusion coefficient was determined by fitting the transient current curve with a theoretical one derived from Fick's law. When the potential was stepped between two potentials in the range of 0 to 0.5 V, transient curves were well fitted with the theoretical one, which gaveDLi+ values on the order of 10−8cm2s−1. In contrast, when the potential was stepped between two potentials across 0.5 V, significant deviation was observed. The deviation indicated the presence of trap sites as well as diffusion sites for Li+ions, the former of which is the origin of the irreversible capacity of GC.


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