Synthesis and characterization ofSchiff bases derived from 1:1 and 1:2 condensations of benzoylacetylacetone with N-benzylethylenediamine. Complexes with some divalent metal ions

1995 ◽  
Vol 126 (5) ◽  
pp. 505-518 ◽  
Author(s):  
J. A. Guti�rrez ◽  
J. A. L�pez-Jim�nez ◽  
R. Gavi�o ◽  
H. N�th
2016 ◽  
Vol 45 (14) ◽  
pp. 5989-5998 ◽  
Author(s):  
Thomas W. Myers ◽  
Tobias J. Sherbow ◽  
James C. Fettinger ◽  
Louise A. Berben

The synthesis and electronic structure of bis(imino)pyridine (I2P) complexes of the divalent metal ions, Zn(ii) and Mg(ii) are reported, and a correlation between the ligand Cim–Cpy bond lengths with the ligand torsion angle is described. Structural comparison with a new complex of Al(iii) and previously reported Al(iii) complexes is included.


2010 ◽  
Vol 7 (2) ◽  
pp. 409-418
Author(s):  
Dilip C. Sawant ◽  
A. Venkatchallam ◽  
R. G. Deshmukh

Synthesis and characterization of a newN"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1:2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure.


2018 ◽  
Vol 16 (37) ◽  
pp. 79-87
Author(s):  
Shahinaz A. Hamad Al-Dabbagh

In this work, Schiff base ligands L1: N, N-bis (2-hydroxy-1-naphthaldehyde) hydrazine, L2: N, N-bis (salicylidene) hydrazine, and L3:N –salicylidene- hydrazine were synthesized by condensation reaction. The prepared ligands were reacted with specific divalent metal ions such as (Mn2+, Fe2+, Ni2+) to prepare their complexes. The ligands and complexes were characterized by C.H.N, FT-IR, UV-Vis, solubility, melting point and magnetic susceptibility measurements. The results show that the ligands of complexes (Mn2+, Fe2+) have octahedral geometry while the ligands of complexes (Ni2+) have tetrahedral geometry.


1991 ◽  
Vol 81 (4) ◽  
pp. 462-466 ◽  
Author(s):  
Maria Fabiana Drincovich ◽  
Alberto A. Iglesias ◽  
Carlos S. Andreo

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