Local structure and valence of impurity ions in oxides by TDPAC and Mössbauer emission spectroscopy

1995 ◽  
Vol 190 (2) ◽  
pp. 215-224 ◽  
Author(s):  
F. Ambe ◽  
Y. Ohkubo ◽  
S. Ambe ◽  
Y. Kobayashi ◽  
T. Okada ◽  
...  
Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 789 ◽  
Author(s):  
Tomasz Bodziony ◽  
Slawomir Maksymilian Kaczmarek

The relationship between the g-shift and the local structure of the Ce3+ paramagnetic center with axial symmetry were investigated for four BaWO4 single crystals doped with Ce and codoped with Na. Based on g-shift the displacements of Ce3+ ions are determined. The g-shift method yields displacements of impurity ions in good agreement with the superposition model (SPM) and the perturbation methods (PM) predictions. The structural analysis of the paramagnetic ions and its surrounding in the BaWO4 unit cell was also conducted.


1997 ◽  
Vol 65 (2) ◽  
pp. 183-189 ◽  
Author(s):  
E.Z. Kurmaev ◽  
V.R. Galakhov ◽  
S.N. Shamin ◽  
V.I. Sokolov ◽  
R.E. Hummel ◽  
...  

2021 ◽  
Vol 26 ◽  
pp. 100905
Author(s):  
N. Yoneda ◽  
T. Shikama ◽  
K. Hanada ◽  
S. Mori ◽  
T. Onchi ◽  
...  

Author(s):  
R. F. Egerton

An important parameter governing the sensitivity and accuracy of elemental analysis by electron energy-loss spectroscopy (EELS) or by X-ray emission spectroscopy is the signal/noise ratio of the characteristic signal.


Author(s):  
G.E. Ice

The increasing availability of synchrotron x-ray sources has stimulated the development of advanced hard x-ray (E≥5 keV) microprobes. With new x-ray optics these microprobes can achieve micron and submicron spatial resolutions. The inherent elemental and crystallographic sensitivity of an x-ray microprobe and its inherently nondestructive and penetrating nature will have important applications to materials science. For example, x-ray fluorescent microanalysis of materials can reveal elemental distributions with greater sensitivity than alternative nondestructive probes. In materials, segregation and nonuniform distributions are the rule rather than the exception. Common interfaces to whichsegregation occurs are surfaces, grain and precipitate boundaries, dislocations, and surfaces formed by defects such as vacancy and interstitial configurations. In addition to chemical information, an x-ray diffraction microprobe can reveal the local structure of a material by detecting its phase, crystallographic orientation and strain.Demonstration experiments have already exploited the penetrating nature of an x-ray microprobe and its inherent elemental sensitivity to provide new information about elemental distributions in novel materials.


1982 ◽  
Vol 43 (C9) ◽  
pp. C9-43-C9-46 ◽  
Author(s):  
A. Sadoc ◽  
A. M. Flank ◽  
D. Raoux ◽  
P. Lagarde

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-423-C8-426
Author(s):  
H. OYANAGI ◽  
Y. TAKEDA ◽  
T. MATSUSHITA ◽  
T. ISHIGURO ◽  
A. SASAKI

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-403-C8-406
Author(s):  
N. MOTTA ◽  
A. BALZAROTTI ◽  
P. LETARDI
Keyword(s):  

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