Symmetry of generalized mean-square vibration amplitudes and their effect on mean and equilibrium bond lengths in benzene, pyridine, and N-oxypyridine

1998 ◽  
Vol 65 (2) ◽  
pp. 196-200 ◽  
Author(s):  
K. V. Berezin ◽  
É. K. Kosterina
Author(s):  
Kiyohiko Uehara ◽  
◽  
Takumi Koyama ◽  
Kaoru Hirota ◽  

Theoretical aspects are provided for inference based on α-cuts and generalized mean (α-GEMII). In order to clarify the basic properties of the inference, fuzzy tautological rules (FTRs) are focused on, which are composed by setting fuzzy sets in consequent parts identical to those in antecedent parts of initially given fuzzy rules. It is mathematically proved that the consequences deduced with FTRs are closer to given facts as the number of FTRs increases. The aspects provided in this paper are appropriate from axiomatic viewpoints and can contribute to interpretability in fuzzy systems constructed with α-GEMII. They are not obtained in conventional methods based on the compositional rule of inference. Simulations are performed by evaluating difference (mean square errors) between given facts and deduced consequences under the condition that convex and symmetric fuzzy sets are given as facts. Their results show that the difference becomes smaller as the number of FTRs increases. Thereby, it is confirmed that α-GEMII has an advantage in the interpretability with respect to FTRs over the conventional methods.


1969 ◽  
Vol 9 (7) ◽  
pp. 1033-1034
Author(s):  
Nitish K. Sanyal ◽  
A.N. Pandey ◽  
H.S. Singh
Keyword(s):  

1970 ◽  
Vol 48 (7) ◽  
pp. 1151-1154 ◽  
Author(s):  
H. D. Grundy ◽  
I. D. Brown

The crystal structures of K2ReCl6, K2ReBr6, and K2PtBr6 have been refined using data collected on a single-crystal X-ray diffractometer to give weighted agreement indices ranging from 0.026 to 0.054 for 75 to 90 nonequivalent reflections. The following bond lengths were obtained: Re—Cl = 235 pm, Re—Br = 248 pm, Pt—Br = 246 pm, K—Cl = 348 pm, and K—Br = 367 and 364 pm in the Re and Pt compounds, respectively. The differences in the root-mean-square angles of libration of the MX62− ions in these and a number of isomorphous crystals are discussed.


1981 ◽  
Vol 24 (1) ◽  
pp. 23-42
Author(s):  
Antonio Cantoni ◽  
Robin Evans ◽  
Ken Kwong

1968 ◽  
Vol 46 (16) ◽  
pp. 2641-2643 ◽  
Author(s):  
Alpha O. Diallo

The theory of the generalized mean amplitudes of vibration has been applied to the C3S2 molecule, which possesses a linear symmetrical structure. The numerical values of the force constants and the mean square parallel and perpendicular amplitudes at 298°K of all bonded and non-bonded pairs of atoms are calculated from spectroscopic vibrational frequencies by the Cyvin and Morino–Hirota methods, utilizing the symmetry coordinates. The "shrinkage" effect constants are also evaluated by means of the perpendicular mean square amplitudes.


1967 ◽  
Vol 21 ◽  
pp. 473-480 ◽  
Author(s):  
Jon Brunvoll ◽  
Peder Kierkegaard ◽  
Johan Santesson ◽  
Pär Holmberg ◽  
G. Eriksson ◽  
...  

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