Theoretical evaluation of sound velocities in binary liquid mixtures containing triethyl amine

1975 ◽  
Vol 82 (6) ◽  
pp. 217-223 ◽  
Author(s):  
K. Ravindra Prasad ◽  
K. C. Reddy
Keyword(s):  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Triethyl Amine ◽  
Sound Velocities

scholarly journals Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of 1-Bromopropane in Chlorobenzene at 303.15, 308.15, 313.15 and 318.15 K

2014 ◽  
Vol 30 ◽  
pp. 9-17
Author(s):  
Ch. Praveen Babu ◽  
G. Pavan Kumar ◽  
B. Nagarjun ◽  
K. Samatha
Keyword(s):  
Intermolecular Interactions ◽  
Theoretical Models ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Theoretical velocities of binary liquid mixtures of 1-bromopropane with chlorobenzene at 2 MHz and four different temperatures 303.15, 308.15, 313.15 and 318.15 K, have been evaluated as a function of concentration and temperature. The experimental values are compared with theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Impedance Relation, Rao’s Specific Velocity Method, Junjie’s relations and Free Length Theory. In the chosen system there is a good agreement between experimental and theoretical values calculated by Nomoto’s theory. The deviation in the variation of U2exp/U2imx from unity has also been evaluated for explaining the non ideality in the mixtures. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.

Sound Velocities in Binary Liquid Mixtures

1959 ◽  
Vol 460 (1-2) ◽  
pp. 53-56
Author(s):  
Harkrishan Singh ◽  
R. S. Seth
Keyword(s):  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Binary Liquid ◽  
Sound Velocities

scholarly journals Theoretical Evaluation of Refractive Index in Binary Liquid Mixtures

2005 ◽  
Vol 2 (2) ◽  
pp. 157-160 ◽  
Author(s):  
Shipra Baluja ◽  
Nirmal Pandaya ◽  
Nikunj Kachhadia ◽  
Asif Solanki
Keyword(s):  
Refractive Index ◽  
Diethyl Malonate ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Mixing Rules ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Experimental Values

The density and refractive index (RI) for four binary liquid mixtures: diethyl malonate + dimethylformamide (DEM+DMF), diethyl malonate + Hexane (DEM+HEX), diethyl malonate + tetrahydrofuran (DEM+THF), diethyl malonate + 1,4-dioxane (DEM+DO) have been measured. The experimental values are compared with those calculated from Lorentz-Lorentz, Heller, Newton and Gladstone -Dale mixing rules.

scholarly journals Experimental and Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of Anisaldehyde and Toluene at Different Temperatures

2011 ◽  
Vol 8 (3) ◽  
pp. 977-981
Author(s):  
CH. Srinivasu ◽  
K. Narendra ◽  
CH. Kalpana
Keyword(s):  
Ultrasonic Velocity ◽  
Theoretical Models ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Theoretical velocities of binary liquid mixtures of anisaldehyde with toluene at 303.15, 308.15, 313.15 and 318.15 K have been evaluated by using theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Schaff’s collision factor theory and Junjie’s relations. Density and ultrasonic velocity of these mixtures have also been measured as a function of concentration and temperature and the experimental values are compared with the theoretical values. A good agreement has been found between experimental and Nomoto’s theoretical ultrasonic velocities. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.

scholarly journals Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of Anisaldehyde with Some Alcoxyethanols at Different Temperatures

2012 ◽  
Vol 2012 ◽  
pp. 1-12 ◽  
Author(s):  
Zareena Begum ◽  
P. B. Sandhya Sri ◽  
C. Rambabu
Keyword(s):  
Interaction Parameter ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Ideal Mixing ◽  
Different Temperatures ◽  
Relation Ideal ◽  
Molecular Interaction Parameter

Ultrasonic velocities and densities of the binary liquid mixtures of anisaldehyde with alcoxyethanols like methoxyethanol (MOE), ethoxyethanol (EOE), and butoxyethanol (BOE) have been measured at temperatures 303.15 K, 308.15 K, 313.15 K, and 318.15 K over the entire composition range of mole fractions. The theoretical values of ultrasonic velocity were evaluated using Nomoto's relation (), impedance relation (), ideal mixing relation (), Jungie's relation (), and Rao’s specific velocity relation (). The molecular interaction parameter () has been evaluated from the values of experimental and theoretical velocities. The variation of this interaction parameter with the composition mixture has been discussed in terms of molecular interactions.

scholarly journals Theoretical Evaluation of Internal Pressure in Ternary and Sub-Binary Liquid Mixtures at Various Temperatures

2013 ◽  
Vol 4 ◽  
pp. 82-95
Author(s):  
J. Madhumitha ◽  
N. Santhi ◽  
G. Alamelumangai ◽  
M. Emayavaramban
Keyword(s):  
Internal Pressure ◽  
Liquid Mixture ◽  
Liquid Mixtures ◽  
Butyl Alcohol ◽  
Molar Refraction ◽  
Binary Liquid Mixtures ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Experimental Values ◽  
Internal Pressures

The Internal pressures of Ternary and their Sub-Binary liquid mixtures of benzene(1) + hexane(2) + sec-butyl alcohol(3) were calculated using density, velocity and molar refraction from the temperature range of 303.15K-318.15K. For the Binary liquid mixtures, the Experimental Internal pressure values were correlated through an equation proposed by Andiappan et.al. For the Ternary liquid mixture, the Experimental Internal pressure values were correlated through an equation proposed by us. The Experimental values and the Theoretical values are in close agreement with each other

scholarly journals Theoretical Evaluation of Ultrasonic Velocity in Binary Liquid Mixtures of Alcohols [S] + Benzene

2013 ◽  
Vol 7 ◽  
pp. 18-35 ◽  
Author(s):  
N. Santhi ◽  
P.L. Sabarathinam ◽  
J. Madhumitha ◽  
G. Alamelumangai ◽  
M. Emayavaramban
Keyword(s):  
Ultrasonic Velocity ◽  
Molecular Interaction ◽  
Composition Range ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Experimental Values ◽  
Molecular Interaction Parameter

Ultrasonic velocities and densities of the binary liquid mixtures of benzene with 1-propanol, 2-propanol, 1-butanol, 2-butanol and 3-butanol at 303.15 to 318.15 K, over the entire composition range were measured. The theoretical values of ultrasonic velocity were evaluated using the Nomoto’s Relation (NR), Ideal Mixture Relation (IMR), Free Length Theory (FLT) and Collision Factor Theory (CFT). The validity of these relations and theories were tested by comparing the computed sound velocities with experimental values. Further, the molecular interaction parameter (α) was computed by using the experimental and the theoretical ultrasonic velocity values. The variation of this parameter with composition of the mixtures has been discussed in terms of molecular interaction in these mixtures.

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