scholarly journals Using zircon trace element composition to assess porphyry copper potential of the Guichon Creek batholith and Highland Valley Copper deposit, south-central British Columbia

Author(s):  
Robert G. Lee ◽  
Kevin Byrne ◽  
Michael D’Angelo ◽  
Craig J.R. Hart ◽  
Pete Hollings ◽  
...  
2019 ◽  
Vol 114 (7) ◽  
pp. 1365-1388 ◽  
Author(s):  
Hervé Rezeau ◽  
Robert Moritz ◽  
Jörn-Frederik Wotzlaw ◽  
Samvel Hovakimyan ◽  
Rodrik Tayan

Abstract The trace element composition of zircon, especially in tandem with U-Pb geochronology, has become a powerful tool for tracing magmatic processes associated with the formation of porphyry copper deposits. However, the use of the redox-sensitive Eu and Ce anomalies as a potential mineral exploration proxy is controversial. This study presents a comprehensive, temporally constrained data set of zircon trace element compositions (n = 645) for three compositionally distinct magmatic series identified in the Meghri-Ordubad pluton, southernmost Lesser Caucasus. The 30 million years of Cenozoic magmatism in the Meghri-Ordubad pluton are associated with several ore-forming pulses leading to the formation of porphyry copper deposits and epithermal-style mineralization. Our zircon geochemical data constrain the thermal and chemical evolution of this complex intrusive suite and allow an evaluation of the usefulness of zircon as a mineral exploration proxy for porphyry copper deposits. Our results combined with Rayleigh fractionation modeling indicate that the trace element composition of zircon (Th/U, Hf, Ti, YbN/DyN, Eu anomalies) is influenced by the composition and the water concentration of the parental magma, as well as by co-crystallizing titanite and apatite. In contrast, the variations of Ce anomalies remain difficult to explain by magmatic processes and could rather be ascribed to relative fluctuations of the redox conditions. In the Meghri-Ordubad pluton, we do not observe any systematic patterns between the trace element composition in zircons and the different ore-forming pulses. This questions the reliability of using the trace element composition in zircon as an exploration mineral proxy, and it rather emphasizes that a good knowledge of the entire magmatic evolution of a metallogenic province is required.


2021 ◽  
Author(s):  
Robert G. Lee ◽  
Alain Plouffe ◽  
Travis Ferbey ◽  
Craig J.R. Hart ◽  
Pete Hollings ◽  
...  

Abstract The detrital zircons in tills overlying the Guichon Creek batholith, British Columbia, Canada, have trace element concentrations and ages similar to those of zircons from the bedrock samples from which they are interpreted to have been sourced. Rocks from the core of the batholith that host porphyry copper mineralization have distinct zircon compositions relative to the distal, barren margin. We analyzed 296 zircons separated from 12 subglacial till samples to obtain U-Pb ages and trace element compositions. Laser ablation U-Pb ages of the detrital zircons overlap within error with chemical abrasion-thermal ionization mass spectrometry U-Pb ages of the Late Triassic Guichon Creek batholith and confirm that the detrital zircons are likely derived from the batholith. The youngest intrusions of the batholith produced the Highland Valley Copper porphyry deposits and contain distinctive zircons with elevated Eu/EuN* >0.4 attributed to high magmatic water contents and oxidation states, indicating higher porphyry copper potential. Zircon from till samples adjacent to and 9 km down-ice from the mineralized centers have mean Eu/EuN* >0.4, which are indicative of potential porphyry copper mineralization. Detrital zircon grains from more distal up- and down-ice locations (10–15 km) have zircon Eu/EuN* mean values of 0.26 to 0.37, reflecting background values. We conclude that detrital zircon compositions in glacial sediments transported several kilometers can be used to establish the regional potential for porphyry copper mineralization.


2020 ◽  
Vol 115 (7) ◽  
pp. 1413-1442
Author(s):  
Nikolett Kovacs ◽  
Murray M. Allan ◽  
James L. Crowley ◽  
Maurice Colpron ◽  
Craig J.R. Hart ◽  
...  

Abstract Late Triassic to Early Jurassic porphyry Cu mineralization is common in British Columbia, yet there are few age-equivalent porphyry occurrences in Yukon. This study presents new data for the enigmatic Carmacks Copper Cu-Au-Ag deposit in south-central Yukon, Canada, which is hosted in amphibolite facies metamorphic inliers within the Early Jurassic Granite Mountain batholith. Sulfide mineralization occurs mainly as net-textured bornite and chalcopyrite in leucosome, and as chalcopyrite ± pyrite blebs and disseminations in amphibolite and quartz-plagioclase-biotite schist. Several studies suggest that the Carmacks Copper deposit and the nearby Minto deposit are related to porphyry belts in British Columbia, but constraining the timing of alteration, mineralization, and metamorphism has been difficult. This study establishes a geologic and high-precision geochronologic framework for sulfide mineralization and its host rocks at the Carmacks Copper deposit, using Re-Os dating of molybdenite, and chemical abrasion-thermal ionization mass spectrometry (CA-TIMS) analysis of both whole zircon grains and laser-cut fragments of complexly zoned zircon grains. Our data indicate that the igneous protolith of the metamorphic inliers formed at 217.53 ± 0.16 Ma, followed by peak metamorphism at amphibolite facies at 205.82 ± 0.23 Ma, which occurred prior to Granite Mountain batholith emplacement but subsequent to Cu-Au-Ag mineralization of the protolith. An early phase of the Granite Mountain batholith was emplaced at 199.84 ± 0.14 Ma, followed by the main phase at 195 to 194 Ma. A second generation of metamorphic zircon in migmatite at 196.01 ± 0.12 Ma represents a partial melting event associated with Granite Mountain batholith emplacement. Two petrographically distinct populations of molybdenite are present in unstrained, net-textured copper sulfides. A sample dominated by strained molybdenite yielded an 187Re/187Os age of 212.5 ± 1.0 Ma, which represents the minimum mineralization age of the protolith. A sample dominated by euhedral grains yielded an 187Re/187Os age of 198.5 ± 0.9 Ma, constraining the maximum age of sulfide remobilization. These results indicate that primary mineralization is >212.5 Ma and potentially coeval with the ~217.5 Ma generation of Late Triassic magmatism. The mineralized protolith, best interpreted as the potassic alteration zone of a Late Triassic (~217–213 Ma) porphyry Cu-Au system, was metamorphosed to amphibolite facies at ~206 Ma, and subsequently migmatized during 200 to 194 Ma intrusion of the Granite Mountain batholith. The chalcopyrite-bornite-dominant assemblage in neosome precipitated from an immiscible Cu-Fe-S melt phase that partly consumed xenocrystic molybdenite and reprecipitated new molybdenite grains. The Carmacks Copper deposit and the related Minto deposit are remnants of a Late Triassic porphyry belt, where a significant fraction of the original metal endowment was likely lost through digestion of mineralized rocks by midcrustal magma in the Early Jurassic. These Yukon deposits are rare examples of metamorphosed porphyry Cu systems in the global geologic record, where rapid tectonic burial following mineralization was the principal factor in their preservation.


2017 ◽  
Author(s):  
Ryan S. Jackson ◽  
◽  
Horton Newsom ◽  
Agnes Cousin ◽  
Valérie Payre ◽  
...  

2020 ◽  
Vol 58 (12) ◽  
pp. 1321-1330
Author(s):  
K. G. Sukhanova ◽  
S. G. Skublov ◽  
O. L. Galankina ◽  
E. V. Obolonskaya ◽  
E. L. Kotova

Author(s):  
Tereza Koláčková ◽  
Daniela Sumczynski ◽  
Vratislav Bednařík ◽  
Štěpán Vinter ◽  
Jana Orsavová ◽  
...  

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