Synthesis and dilute aqueous solution properties of ester functionalized cationic gemini surfactants having different ethylene oxide units as spacer

2014 ◽  
Vol 292 (7) ◽  
pp. 1685-1692 ◽  
Author(s):  
Avinash Bhadani ◽  
Takeshi Endo ◽  
Kenichi Sakai ◽  
Hideki Sakai ◽  
Masahiko Abe
Keyword(s):  
Aqueous Solution ◽  
Ethylene Oxide ◽  
Gemini Surfactants ◽  
Solution Properties ◽  
Cationic Gemini Surfactants ◽  
Dilute Aqueous Solution

Synthesis, Characterization and Solution Properties of Novel Cationic Ester-Based Gemini Surfactants

2019 ◽  
Vol 233 (5) ◽  
pp. 707-720 ◽  
Author(s):  
Manorama Panda ◽  
Nazish Fatma ◽  
Mohammad Kamil
Keyword(s):  
Gemini Surfactants ◽  
Alkyl Chain ◽  
Solution Properties ◽  
H Nmr ◽  
Surfactant Solutions ◽  
Cationic Gemini Surfactants ◽  
Ft Ir ◽  
M 12 ◽  
Dimeric Surfactant ◽  
Ft Ir Spectroscopy

Abstract The present investigation involves the synthesis of a series of novel green ethylene oxide-linked diester-functionalized cationic gemini surfactants 2,2′-[(oxybis(ethane-1,2-diyl))bis(oxy)]bis(N-alkyl-N,N-dimethyl-2-oxoethanaminium) dichloride (Cm-DEG-Cm; m = 12, 14, 16). These compounds were characterized by 1H-NMR, MS-ESI (+), FT-IR spectroscopy and elemental analysis; their solution properties were evaluated by surface tension and rheology measurements. The dimeric surfactant, Cm-DEG-Cm, possesses improved physicochemical properties as compared to its monomeric counterpart. Much lower critical micelle concentration (cmc) makes the cationic gemini surfactants more useful for the biomedical, pharmaceutical, industrial and academic sectors. Longer the alkyl chain of surfactants lower are the cmc values, the order is C16-DEG-C16 < C14-DEG-C14 < C12-DEG-C12. For all the three synthesized gemini surfactants no cloud point was noticed in between the temperatures 0 °C to 100 °C at the concentrations 0.002 mM, 0.02 mM and 0.2 mM of the aqueous surfactant solutions which is a beneficial factor for the use of these amphiphiles in various areas of application.

scholarly journals Poly(ethylene oxide)-block-poly(n-butyl acrylate)-block-poly(acrylic acid) triblock terpolymers with highly asymmetric hydrophilic blocks: synthesis and aqueous solution properties

Soft Matter ◽  
2013 ◽  
Vol 9 (36) ◽  
pp. 8745 ◽  
Author(s):  
Petar D. Petrov ◽  
Krassimira Yoncheva ◽  
Pavlina Mokreva ◽  
Spiro Konstantinov ◽  
Juan M. Irache ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Acrylic Acid ◽  
Ethylene Oxide ◽  
Butyl Acrylate ◽  
Solution Properties ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Triblock Terpolymers ◽  
Poly Acrylic Acid

Micellization properties of cationic gemini surfactants in aqueous solution

2013 ◽  
Vol 558 ◽  
pp. 29-35 ◽  
Author(s):  
K. Łudzik ◽  
H. Piekarski ◽  
K. Kubalczyk ◽  
M. Wasiak
Keyword(s):  
Aqueous Solution ◽  
Gemini Surfactants ◽  
Cationic Gemini Surfactants

Aqueous solution properties of oligo- and poly(ethylene oxide) by static light scattering and intrinsic viscosity

Polymer ◽  
1997 ◽  
Vol 38 (12) ◽  
pp. 2885-2891 ◽  
Author(s):  
Seigou Kawaguchi ◽  
Genji Imai ◽  
Junto Suzuki ◽  
Akira Miyahara ◽  
Toshiaki Kitano ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Light Scattering ◽  
Ethylene Oxide ◽  
Intrinsic Viscosity ◽  
Static Light Scattering ◽  
Solution Properties ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Aqueous solution behaviour and solubilisation properties of octadecyl cationic gemini surfactants and their comparison with their amide gemini analogues

Soft Matter ◽  
2018 ◽  
Vol 14 (5) ◽  
pp. 754-764 ◽  
Author(s):  
J. Woch ◽  
J. Iłowska ◽  
Z. Hordyjewicz-Baran ◽  
S. Arabasz ◽  
B. Kaczmarczyk ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Gemini Surfactants ◽  
Amide Group ◽  
Aggregation Behaviour ◽  
Cationic Gemini Surfactants ◽  
Solution Behaviour

The aggregation behaviour of octadecyl gemini surfactants in water was related to the behaviour of their amide group containing analogues.

Experimental and Theoretical Approach to Mixed Systems of Non-Ionic Cremophor EL and Cationic Gemini Surfactants in Aqueous Solution

2015 ◽  
Vol 229 (3) ◽  
Author(s):  
Andleeb Z. Naqvi ◽  
Sahar Noori ◽  
Kabir-ud-Din
Keyword(s):  
Aqueous Solution ◽  
Surface Tension ◽  
Gemini Surfactants ◽  
Cremophor El ◽  
Practical Applications ◽  
Surfactant Solutions ◽  
Cationic Gemini Surfactants ◽  
Mixing Behavior ◽  
Different Types ◽  
Mixed Systems

AbstractSurfactant solutions in practical applications usually are mixtures of different types, especially ionic and nonionic ones. The mixing behavior of nonionic Cremophor EL-cationic gemini systems was therefore investigated by surface tension measurements. The Gemini surfactants used were of the type alkanediyl –

Difference in dilute aqueous solution behavior between poly(ethylene glycol) and poly(ethylene oxide)

2017 ◽  
Vol 50 (3) ◽  
pp. 231-237 ◽  
Author(s):  
Akihisa Nakamura ◽  
Yutaka Aoki ◽  
Masashi Osa ◽  
Daichi Ida ◽  
Takenao Yoshizaki
Keyword(s):  
Aqueous Solution ◽  
Ethylene Oxide ◽  
Ethylene Glycol ◽  
Poly Ethylene Glycol ◽  
Solution Behavior ◽  
Dilute Aqueous Solution ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene
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