Role of acceptor guests in tuning optoelectronic properties of benzothiadiazole core based non-fullerene acceptors for high-performance bulk-heterojunction organic solar cells

2021 ◽  
Vol 27 (8) ◽  
Author(s):  
Muhammad Yasir Mehboob ◽  
Riaz Hussain ◽  
Zobia Irshad ◽  
Muhammad Adnan
2018 ◽  
Vol 6 (30) ◽  
pp. 14675-14680 ◽  
Author(s):  
Xuan Zhou ◽  
Wei Tang ◽  
Pengqing Bi ◽  
Lei Yan ◽  
Xingzhu Wang ◽  
...  

Supramolecular self-assembly of a porphyrin donor with J-aggregates affords higher performance with a PC71BM acceptor in bulk heterojunction organic solar cells.


Author(s):  
Minas M. Stylianakis ◽  
Dimitriοs M. Kosmidis ◽  
Katerina Anagnostou ◽  
Christos Polyzoidis ◽  
Miron Krassas ◽  
...  

A novel solution-processed graphene-based material was synthesized by treating graphene oxide (GO) with 2,5,7-trinitro-9-oxo-fluorenone-4-carboxylic acid (TNF-COOH) moieties, via simple synthetic routes. The yielded molecule N-[(carbamoyl-GO)ethyl]-N’-[(carbamoyl)-(2,5,7-trinitro-9-oxo-fluorene)] (GO-TNF) was thoroughly characterized and it was shown that it presents favorable highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels to function as a bridge component between the polymeric donor poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl}) (PTB7) and the fullerene derivative acceptor [6,6]-phenyl-C71-butyric-acid-methylester (PC71BM). In this context, a GO-TNF based ink was prepared and directly incorporated within the binary photoactive layer, in different volume ratios (1-3% ratio to the blend), for the effective realization of inverted ternary organic solar cells (OSCs) of the structure ITO/PFN/PTB7:GO-TNF:PC71BM/MoO3/Al. The addition of 2% v/v GO-TNF ink led to a champion power conversion efficiency (PCE) of 8.71% that was enhanced by ~13% as compared to the reference cell.


2018 ◽  
Vol 63 ◽  
pp. 384-391 ◽  
Author(s):  
Se Jin Lee ◽  
Sang Bong Lee ◽  
Sung Cheol Yoon ◽  
Eun Young Choi ◽  
Choon Sup Yoon

2016 ◽  
Vol 8 (10) ◽  
pp. 6309-6314 ◽  
Author(s):  
Jurgen Kesters ◽  
Sanne Govaerts ◽  
Geert Pirotte ◽  
Jeroen Drijkoningen ◽  
Michèle Chevrier ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ruimin Zhou ◽  
Zhaoyan Jiang ◽  
Chen Yang ◽  
Jianwei Yu ◽  
Jirui Feng ◽  
...  

AbstractThe high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nanometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.


2012 ◽  
Vol 3 (3) ◽  
pp. 356-363 ◽  
Author(s):  
Wei Lin Leong ◽  
Gregory C. Welch ◽  
Jason Seifter ◽  
Jung Hwa Seo ◽  
Guillermo C. Bazan ◽  
...  

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