scholarly journals Metal oxide electron transport materials for perovskite solar cells: a review

Author(s):  
Kobra Valadi ◽  
Saideh Gharibi ◽  
Reza Taheri-Ledari ◽  
Seckin Akin ◽  
Ali Maleki ◽  
...  
Rare Metals ◽  
2021 ◽  
Author(s):  
Jia-Xing Song ◽  
Xin-Xing Yin ◽  
Zai-Fang Li ◽  
Yao-Wen Li

Abstract As a promising photovoltaic technology, perovskite solar cells (pero-SCs) have developed rapidly over the past few years and the highest power conversion efficiency is beyond 25%. Nowadays, the planar structure is universally popular in pero-SCs due to the simple processing technology and low-temperature preparation. Electron transport layer (ETL) is verified to play a vital role in the device performance of planar pero-SCs. Particularly, the metal oxide (MO) ETL with low-cost, superb versatility, and excellent optoelectronic properties has been widely studied. This review mainly focuses on recent developments in the use of low-temperature-processed MO ETLs for planar pero-SCs. The optical and electronic properties of widely used MO materials of TiO2, ZnO, and SnO2, as well as the optimizations of these MO ETLs are briefly introduced. The commonly used methods for depositing MO ETLs are also discussed. Then, the applications of different MO ETLs on pero-SCs are reviewed. Finally, the challenge and future research of MO-based ETLs toward practical application of efficient planar pero-SCs are proposed. Graphical abstract


Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2207 ◽  
Author(s):  
Md. Shahiduzzaman ◽  
Shoko Fukaya ◽  
Ersan Y. Muslih ◽  
Liangle Wang ◽  
Masahiro Nakano ◽  
...  

Perovskite solar cells (PSCs) have appeared as a promising design for next-generation thin-film photovoltaics because of their cost-efficient fabrication processes and excellent optoelectronic properties. However, PSCs containing a metal oxide compact layer (CL) suffer from poor long-term stability and performance. The quality of the underlying substrate strongly influences the growth of the perovskite layer. In turn, the perovskite film quality directly affects the efficiency and stability of the resultant PSCs. Thus, substrate modification with metal oxide CLs to produce highly efficient and stable PSCs has drawn attention. In this review, metal oxide-based electron transport layers (ETLs) used in PSCs and their systemic modification are reviewed. The roles of ETLs in the design and fabrication of efficient and stable PSCs are also discussed. This review will guide the further development of perovskite films with larger grains, higher crystallinity, and more homogeneous morphology, which correlate to higher stable PSC performance. The challenges and future research directions for PSCs containing compact ETLs are also described with the goal of improving their sustainability to reach new heights of clean energy production.


Small ◽  
2019 ◽  
Vol 16 (15) ◽  
pp. 1902579 ◽  
Author(s):  
Yu Zhou ◽  
Xin Li ◽  
Hong Lin

2016 ◽  
Vol 59 (9) ◽  
pp. 757-768 ◽  
Author(s):  
Yuli Xiong ◽  
Tongfa Liu ◽  
Xixi Jiang ◽  
Yaoguang Rong ◽  
Hongwei Han

Solar RRL ◽  
2018 ◽  
Vol 2 (6) ◽  
pp. 1700245 ◽  
Author(s):  
Shizhao Zheng ◽  
Wenlang Li ◽  
Tongtong Su ◽  
Fangyan Xie ◽  
Jian Chen ◽  
...  

2020 ◽  
Vol 8 (38) ◽  
pp. 19768-19787
Author(s):  
Zhiyuan Cao ◽  
Chengbo Li ◽  
Xiaoyu Deng ◽  
Shurong Wang ◽  
Yuan Yuan ◽  
...  

Recent advances of metal oxides beyond TiO2 and SnO2 for electron transport in perovskite solar cells are reviewed from the aspects of nanostructuring, element doping, surface modification, multi-layer design and large-scale fabrication.


2018 ◽  
Vol 122 (30) ◽  
pp. 17088-17095 ◽  
Author(s):  
Fengjiu Yang ◽  
Jiewei Liu ◽  
Hong En Lim ◽  
Yasuhisa Ishikura ◽  
Keisuke Shinokita ◽  
...  

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