A Review on Pd Based Catalysts for CO2 Hydrogenation to Methanol: In-Depth Activity and DRIFTS Mechanistic Study

2019 ◽  
Vol 24 (1) ◽  
pp. 11-37 ◽  
Author(s):  
Opeyemi A. Ojelade ◽  
Sharif F. Zaman
Keyword(s):  
Co2 Hydrogenation ◽  
Mechanistic Study

Mechanistic Study of Pd–Cu Bimetallic Catalysts for Methanol Synthesis from CO2 Hydrogenation

2017 ◽  
Vol 121 (47) ◽  
pp. 26287-26299 ◽  
Author(s):  
Lingna Liu ◽  
Fei Fan ◽  
Zhao Jiang ◽  
Xiufeng Gao ◽  
Jinjia Wei ◽  
...  
Keyword(s):  
Methanol Synthesis ◽  
Bimetallic Catalysts ◽  
Co2 Hydrogenation ◽  
Mechanistic Study

Mechanistic study of methanol synthesis from CO2 hydrogenation on Rh-doped Cu(111) surfaces

2019 ◽  
Vol 466 ◽  
pp. 26-36 ◽  
Author(s):  
Lingna Liu ◽  
Fei Fan ◽  
Miaomiao Bai ◽  
Fan Xue ◽  
Xiangrong Ma ◽  
...  
Keyword(s):  
Methanol Synthesis ◽  
Co2 Hydrogenation ◽  
Mechanistic Study

Mechanistic Study of Low-Temperature CO2 Hydrogenation over Modified Rh/Al2O3 Catalysts

ACS Catalysis ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 6275-6284 ◽  
Author(s):  
Denise Heyl ◽  
Uwe Rodemerck ◽  
Ursula Bentrup
Keyword(s):  
Low Temperature ◽  
Co2 Hydrogenation ◽  
Mechanistic Study

Mechanistic study of proliferation induced by Angelica sinensis in gastric epithelial cells

2001 ◽  
Vol 120 (5) ◽  
pp. A145-A145
Author(s):  
C CHO ◽  
Y YE ◽  
E LIU ◽  
V SHIN ◽  
N SHAM
Keyword(s):  
Epithelial Cells ◽  
Mechanistic Study ◽  
Angelica Sinensis ◽  
Gastric Epithelial Cells

Mechanistic study on the cardioprotective and chemosensitizing effects of a novel danshensu derivative

Planta Medica ◽  
2014 ◽  
Vol 80 (16) ◽  
Author(s):  
L Wang ◽  
L Shan ◽  
G Cui ◽  
Y Chen ◽  
J li ◽  
...  
Keyword(s):  
Mechanistic Study

Mechanistic Study and Development of Catalytic Reactions of Sm(II)

2018 ◽  
Author(s):  
Sandepan Maity ◽  
Robert Flowers
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Proton Donor ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Mechanistic Studies ◽  
Cyclization Reactions ◽  
Mechanistic Approach ◽  
Donor Source

Despite the broad utility and application of SmI<sub>2</sub>in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivalents of electrons. We report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magnesium reductant and trimethyl silyl chloride in concert with a non-coordinating proton donor source. Reactions using this approach permitted reductions with as little as 1 mol% Sm. The mechanistic approach enabled catalysis employing HMPA as a ligand, facilitating the development of catalytic Sm(II) 5-<i>exo</i>-<i>trig </i>ketyl olefin cyclization reactions.

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