Influence of acid-base and oxidation-reduction reactions on the distribution of stable impurities and radionuclides in “soil-liquid radioactive waste” system

2003 ◽  
Vol 53 (S1) ◽  
pp. A621-A627
Author(s):  
A. S. Kozyrev ◽  
V. A. Matyukha ◽  
E. N. Semyonov ◽  
V. K. Larin
Keyword(s):  
Radioactive Waste ◽  
Liquid Radioactive Waste ◽  
Acid Base ◽  
Reduction Reactions ◽  
Oxidation Reduction

New Approaches to Cleaning Liquid Radioactive Waste

2015 ◽  
Vol 11 (3) ◽  
pp. 53-67
Author(s):  
Yu.L. Zabulonov ◽  
Keyword(s):  
Radioactive Waste ◽  
Liquid Radioactive Waste ◽  
New Approaches

New Approaches to Cleaning of Liquid Radioactive Waste

2015 ◽  
Vol 11 (3) ◽  
pp. 47-58
Author(s):  
Yu.L. Zabulonov ◽  
Keyword(s):  
Radioactive Waste ◽  
Liquid Radioactive Waste ◽  
New Approaches

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Feedback Controlled Chemical Reactor with Feed of Two Reaction Components with Spectrophotometric Indication

1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek
Keyword(s):  
Sulfuric Acid ◽  
Negative Feedback ◽  
Chemical Reactor ◽  
Reduction Reactions ◽  
Oxidation Reduction

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.

Volumetric studies in oxidation-reduction reactions

1958 ◽  
Vol 19 ◽  
pp. 10-11 ◽  
Author(s):  
Balwant Singh ◽  
Sardul Singh
Keyword(s):  
Reduction Reactions ◽  
Oxidation Reduction
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