3D Metal–Organic Framework Based on Cadmium Complex of Pyrazine-2,3,5,6-tetracarboxylic Acid

2011 ◽  
Vol 41 (8) ◽  
pp. 1245-1248 ◽  
Author(s):  
Li-Hua Zhao ◽  
Ai-Hong Yang ◽  
Ying-Ping Quan ◽  
Hong-Ling Gao ◽  
Jian-Zhong Cui
Keyword(s):  
Metal Organic Framework ◽  
Cadmium Complex ◽  
Tetracarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

Eu-MOF and its mixed-matrix membranes as fluorescent sensor for quantitative ratiometric pH and folic acid detection, and visible fingerprint identifying

2021 ◽  
Author(s):  
Yansong Jiang ◽  
Yating Huang ◽  
Xiangxiang Shi ◽  
Zijing Lu ◽  
Jiamo Ren ◽  
...  
Keyword(s):  
Folic Acid ◽  
Fluorescent Sensor ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Mixed Matrix Membranes ◽  
Tetracarboxylic Acid ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

Here, we demonstrate the assembly of a new stable lanthanide-based metal-organic framework (MOF), Eu(HDPB)(phen) (1) (HDPB = (1,1ʹ:3ʹ,1ʹʹ-terphenyl)-3,3ʹʹ,5,5ʹʹ-tetracarboxylic acid, phen = 1,10-phenanthroline), with a three-dimensional framework under solvothermal conditions. 1...

Synthesis, structure and temperature sensing of a lanthanide-organic framework constructed from a pyridine-containing tetracarboxylic acid ligand

CrystEngComm ◽  
2018 ◽  
Vol 20 (45) ◽  
pp. 7395-7400 ◽  
Author(s):  
Dian Zhao ◽  
Huizhen Wang ◽  
Guodong Qian
Keyword(s):  
High Temperature ◽  
Metal Organic Framework ◽  
Temperature Sensing ◽  
Tetracarboxylic Acid ◽  
High Temperature Range ◽  
Temperature Range ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

A high sensitive, thermostable mixed lanthanide metal–organic framework, Eu0.19Tb0.81PDDI, was developed as a self-calibrated thermometer effective in the high temperature range of 313 to 473 K.

A Noninterpenetrated Metal–Organic Framework Built from an Enlarged Tetracarboxylic Acid for Small Hydrocarbon Separation

2015 ◽  
Vol 15 (8) ◽  
pp. 4071-4074 ◽  
Author(s):  
Jianfeng Cai ◽  
Jiancan Yu ◽  
Hailong Wang ◽  
Xing Duan ◽  
Qi Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Tetracarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Morphology and adsorption of chromium ion on uranium 1,2,4,5-benzenetetracarboxylic acid metal organic framework (MOF)

2016 ◽  
Vol 70 (5) ◽  
pp. 565-572 ◽  
Author(s):  
Remy Vala ◽  
Donbebe Wankasi ◽  
Ezekiel Dikio
Keyword(s):  
Electron Microscopy ◽  
Porous Structure ◽  
Metal Organic Framework ◽  
Tetracarboxylic Acid ◽  
X Ray Diffraction ◽  
Kinetic Determination ◽  
Transmission Electron ◽  
Metal Organic ◽  
Organic Framework

In this paper, we report the synthesis of metal organic framework of uranium 1,2,4,5-benzene tetracarboxylic acid (U-H4btec MOF) by solvothermal method. The obtained MOF was characterized by Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction spectroscopy (XRD), Energy dispersive spectroscopy (EDS), thermogravimetric and differential thermogravimetric analysis (TGA/DTA). The morphology of the uranium 1,2,4,5-benzene tetracarboxylic acid MOF observed by SEM, revealed the presence of flaky porous structure. Adsorption of Cr3+ from aqueous solution onto the uranium 1,2,4,5-benzene tetracarboxylic acid MOF was systematically studied. Langmuir and Freundlich adsorption isotherms were applied to determine the adsorption capacity of the MOF to form a monolayer. Kinetic determination of the adsorption of Cr3+ suggested both chemisorption and physisorption probably due to the presence of carbonyl groups within the MOF and its porous structure.

The multifunctional design of metal-organic framework by applying linker desymmetrization strategy: synergistic catalysis for high CO2-epoxides conversion

2021 ◽  
Author(s):  
Yueying Zhu ◽  
Jiaming Gu ◽  
Xueyue Yu ◽  
Borong Zhang ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Solvothermal Reaction ◽  
Tetracarboxylic Acid ◽  
Copper Metal ◽  
High Co2 ◽  
Synergistic Catalysis ◽  
Metal Organic ◽  
Organic Framework ◽  
Multifunctional Design

Herein, a novel copper metal-organic framework (Cu-MOF), [Cu2(CPTPTA)(H2O)]·CH3NH3+·4H2O·7NMF (1) (H5CPTPTA = 5'-(4-carboxyphenyl)-[1,1':3',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid, NMF = N-methylformamide), has been successfully synthesized via solvothermal reaction. By applying linker desymmetrization strategy, compound 1...

Synthesis of Peripherally Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C–H Arylation and Construction of a Double-Helical Cobalt-Based Metal-Organic Framework

Synthesis ◽  
2020 ◽  
Vol 53 (02) ◽  
pp. 326-331
Author(s):  
Yohji Misaki ◽  
Aya Yoshimura ◽  
Keisuke Henmi ◽  
Hitoshi Kimura ◽  
Ryo Sakakibara ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Metal Organic Framework ◽  
Electrochemical Analysis ◽  
Tetracarboxylic Acid ◽  
Palladium Catalyzed ◽  
Metal Organic ◽  
Hydrolysis Of ◽  
Organic Framework

Peripherally arylated tetrathiafulvalenes with an anthraquinoid spacer (TTFAQs) have been synthesized by using palladium-catalyzed direct C–H arylation of the 1,3-dithiole rings. Electrochemical analysis by cyclic voltammetry has revealed that the new tetraarylated TTFAQs show one pair of simultaneous two-electron transfer waves as the parent TTFAQ does. The hydrolysis of the tetra(p-ethoxycarbonylphenyl)-substituted derivative affords the corresponding tetracarboxylic acid, which forms a new double-helical metal-organic framework upon complexation with cobalt(III) nitrate.

Sign in / Sign up

Export Citation Format

Share Document