The Effect of Aminated Carbon Nanotube and Phosphorus Pentoxide on the Thermal Stability and Flame Retardant Properties of the Acrylonitrile–Butadiene–Styrene

2013 ◽  
Vol 25 (2) ◽  
pp. 541-548 ◽  
Author(s):  
Mohammad Ebadi ◽  
Zahra Mirdamadian ◽  
Davood Ghanbari ◽  
Leila Moradi
Keyword(s):  
Thermal Stability ◽  
Carbon Nanotube ◽  
Flame Retardant ◽  
Acrylonitrile Butadiene Styrene ◽  
Phosphorus Pentoxide ◽  
Flame Retardant Properties ◽  
Butadiene Styrene

Effect of Fumed Silica and Zinc Borate on the Thermogravimetric Analysis Curves of ABS/Magnesium Hydroxide Composite

2014 ◽  
Vol 599-601 ◽  
pp. 183-186
Author(s):  
Zhang Ting Li ◽  
Yue Qun Lu ◽  
Li Li Fan ◽  
Pei Bang Dai ◽  
Xia Su ◽  
...  
Keyword(s):  
Mechanical Property ◽  
Thermal Stability ◽  
Flame Retardant ◽  
Fumed Silica ◽  
Acrylonitrile Butadiene Styrene ◽  
Zinc Borate ◽  
Processing Temperature ◽  
Great Decrease ◽  
Thermal Stability Of ◽  
Butadiene Styrene

For achieving sufficient flame retardancy, high magnesim hydroxide (MH) content is needed in MH flame retardant Acrylonitrile-butadiene-styrene copolymer (ABS) composites (ABS/MH), which will cause a great decrease in mechanical property and difficulty in preparing samples for measurement. We prepared ABS/MH filled high 60.0% flame retardant by compounding ABS and modified flame retardant MH, fumed silica (SiO2) and zinc borate (ZB) via TX-10 phosphate/polyacrylate latex and studied the effect of a small amount of SiO2 and ZB with MH in ABS for improving the thermal decomposition of ABS/MH. The thermal stability of the modified flame retardant could meet the processing temperature of ABS. The incorporation of ZB, SiO2 or SiO2/ZB could improve the thermal stability of ABS/MH.

Flame Retardant ABS with a Novel Polyphosphate Derived from Biomass

2011 ◽  
Vol 284-286 ◽  
pp. 187-192 ◽  
Author(s):  
Yan Zhang ◽  
Xiao Ling Chen ◽  
Zheng Ping Fang
Keyword(s):  
Thermal Stability ◽  
Thermogravimetric Analysis ◽  
Flame Retardant ◽  
Cone Calorimeter ◽  
Fire Retardant ◽  
Acrylonitrile Butadiene Styrene ◽  
Cone Calorimeter Test ◽  
Abs Resin ◽  
Intumescent System ◽  
Butadiene Styrene

Acrylonitrile-butadiene-styrene (ABS) was treated with various formulations containing an intumescent fire retardant, which consists of ammonium polyphosphate (APP) and a novel char-forming agent, poly(diphenolic phenyl phosphate)(poly(DPA-PDCP)). The behaviour of this intumescent system was investigated by thermogravimetric analysis (TGA), LOI test and cone calorimeter test, respectively. The results showed that the addition of poly(DPA-PDCP) enhanced the thermal stability and flame retardancy of ABS/APP. The weight of residues improved with the addition of poly(DPA-PDCP) . SEM investigations of residual char burning after cone calorimeter test revealed that poly(DPA-PDCP) plays an stimulative role in the process of carbonization. The intumescent chars formed from ABS/APP/ poly(DPA-PDCP) composites were intact and strong. It is confirmed that the poly(DPA-PDCP) is an efficient char-forming agent for flame retardant ABS resin.

scholarly journals Synthesis of a novel aluminium salt of nitrogen-containing alkylphosphinate with high char formation to flame retard acrylonitrile–butadiene–styrene

2020 ◽  
Vol 7 (9) ◽  
pp. 200800
Author(s):  
Xue Yang ◽  
Hao Wang ◽  
Xueqing Liu ◽  
Jiyan Liu
Keyword(s):  
Acrylonitrile Butadiene Styrene ◽  
Infrared Spectrometry ◽  
X Ray ◽  
Ethyl Methyl ◽  
Flame Retardant Properties ◽  
The Fourier Transform ◽  
Micro Combustion Calorimeter ◽  
Combustion Calorimeter ◽  
Composition Of Products ◽  
Butadiene Styrene

A novel nitrogen-containing alkylphosphinate salt—aluminium β-(p-nitrobenzamide) ethyl methyl phosphinate (AlNP) was synthesized and used to flame retard acrylonitrile–butadiene–styrene copolymer (ABS). The Fourier transform infrared spectrometry, 1 H, 13 C and 31 P nuclear magnetic resonance and X-ray fluorescent spectroscopy (XRF) were applied to characterize the structure and composition of products. The flame retardancy performance, thermal properties and mechanical strength of the ABS/AlNP with respect to AlNP loading were investigated. AlNP was stable before 330°C and decomposed very slowly with residues high up to 56.1% at 700°C. Adding 25–30 wt% of AlNP alone can make ABS to pass V0 rating in the vertical burning tests (UL 94). The results according to the micro combustion calorimeter, thermogravimetric analysis showed that AlNP can depress the heating release and retard the thermal degradation of the ABS. Scanning electron microscopy observation of the residues from LOI test indicated that AlNP formed the condensed and tough residues layer during combustion; XRF analysis showed that the residues contained phosphorus and aluminium element and nitrogen element was not detected. The compact phosphorus/aluminium-rich substance acted as a barrier to enhance flame-retardant properties of the ABS.

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