Phase transitions and high-temperature crystal chemistry of polymorphous modifications of Cs2(UO2)2(MoO4)

2004 ◽  
Vol 46 (5) ◽  
pp. 438-440 ◽  
Author(s):  
E. V. Nazarchuk ◽  
S. V. Krivovichev ◽  
S. K. Filatov
1989 ◽  
Vol 100 (1) ◽  
pp. 135-141 ◽  
Author(s):  
A. I. Baranov ◽  
V. P. Khiznichenko ◽  
L. A. Shuvalov

2011 ◽  
Vol 96 (2-3) ◽  
pp. 353-363 ◽  
Author(s):  
G. Iezzi ◽  
M. Tribaudino ◽  
G. D. Ventura ◽  
I. Margiolaki

2021 ◽  
Vol 154 (17) ◽  
pp. 174702
Author(s):  
Liam C. Kelsall ◽  
Miriam Peña-Alvarez ◽  
Miguel Martinez-Canales ◽  
Jack Binns ◽  
Chris J. Pickard ◽  
...  

1998 ◽  
Vol 53 (1-2) ◽  
pp. 27-37 ◽  
Author(s):  
M. Windhaus ◽  
B. D. Mosel ◽  
W. Müller-Warmuth

Abstract 57 Fe Mössbauer spectra have been measured at various temperatures between 4.2 K and 300 K for iron langbeinites A 2 Fe 2^04)3 with A = K, NH 4 , Rb, T1 and magnesium, manganese and cadmium lang-beinites doped with Fe" + . The spectra revealed several contributions whose isomer shifts and quadru-pole splittings have been obtained by fitting program routines. For the high-temperature cubic phases two crystallographically non-equivalent iron sites have been identified, characteristic of Fe2+ in the high-spin state. Abrupt changes of the quadrupole couplings indicated phase transitions; in some cases, the spectra have also revealed several sites for Fe2+ in low temperature phases. From the temperature dependences, phase transition temperatures, crystal field splittings and Debye temperatures have been derived.


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