Improved hydrogen storage capacity by hydrogen spillover and fine structural characterization of MIL-100 metal organic frameworks

2014 ◽  
Vol 41 (10) ◽  
pp. 7655-7667 ◽  
Author(s):  
Abhijit Krishna Adhikari ◽  
Kuen-Song Lin ◽  
Chao-Shuen Chang
Keyword(s):  
Hydrogen Storage ◽  
Structural Characterization ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Hydrogen Spillover ◽  
Hydrogen Storage Capacity ◽  
Metal Organic

scholarly journals Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity

2016 ◽  
Vol 52 (50) ◽  
pp. 7826-7829 ◽  
Author(s):  
Ayesha Naeem ◽  
Valeska P. Ting ◽  
Ulrich Hintermair ◽  
Mi Tian ◽  
Richard Telford ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
High Selectivity ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Hydrogen Uptake ◽  
Hydrogen Storage Capacity ◽  
High Hydrogen ◽  
Metal Organic ◽  
Adsorption Of Co

New zirconium based metal–organic framework (UBMOF-31) synthesised using mixed-linker strategy showing permanent porosity, excellent hydrogen uptake, and high selectivity for adsorption of CO2 over N2.

Preparation, Characterization, and Hydrogen Storage Capacity of MIL-53 Metal-Organic Frameworks

2013 ◽  
Vol 13 (4) ◽  
pp. 2549-2556 ◽  
Author(s):  
Kuen-Song Lin ◽  
Abhijit Krishna Adhikari ◽  
Mu-Ting Tu ◽  
Chieh-Hung Wang ◽  
Chao-Lung Chiang
Keyword(s):  
Hydrogen Storage ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Hydrogen Storage Capacity ◽  
Metal Organic

scholarly journals Front Cover: High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal-Organic Frameworks (Energy Technol. 3/2018)

2018 ◽  
Vol 6 (3) ◽  
pp. 441-441 ◽  
Author(s):  
Rafael Balderas-Xicohténcatl ◽  
Phillip Schmieder ◽  
Dmytro Denysenko ◽  
Dirk Volkmer ◽  
Michael Hirscher
Keyword(s):  
Hydrogen Storage ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Hydrogen Storage Capacity ◽  
Front Cover ◽  
Metal Organic

Molecular Modeling Studies on a series of Metal-Organic Frameworks

2004 ◽  
Vol 837 ◽  
Author(s):  
Tae-Bum Lee ◽  
Daejin Kim ◽  
Seung-Hoon Choi ◽  
Eungsung Lee ◽  
Youjin Oh ◽  
...  
Keyword(s):  
Monte Carlo ◽  
Hydrogen Storage ◽  
Density Functional ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Adsorbed Hydrogen ◽  
Grand Canonical Monte Carlo ◽  
Hydrogen Storage Capacity ◽  
Metal Organic ◽  
Grand Canonical

ABSTRACTIn order to explore rational designs and synthetic strategies toward efficient hydrogen storage materials, quantum mechanical calculations and grand canonical Monte Carlo simulations have been carried out on a series of the Metal-Organic Frameworks containing various organic linkers. The calculations for specific surface areas and the shape of frontier orbitals for various frameworks indicate that the hydrogen storage capacity is largely dependent on the effective surface area of the material, rather than the free volume. Based on the iso-electrostatic potential surface from density functional calculations and the theoretical amount of adsorbed hydrogen from the grand canonical Monte Carlo calculations, it was also found that the electron localization around the organic linker plays an important role in the hydrogen storage capacity of Metal-Organic Frameworks. The prediction of the modeling study is supported by the hydrogen adsorption experiments with IRMOF-1 and -3, revealing the more enhanced hydrogen storage capacity of IRMOF-3 compared with that of IRMOF-1 at 77 K and H2 1 atm.

scholarly journals High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal-Organic Frameworks

2017 ◽  
Vol 6 (3) ◽  
pp. 510-512 ◽  
Author(s):  
Rafael Balderas-Xicohténcatl ◽  
Phillip Schmieder ◽  
Dmytro Denysenko ◽  
Dirk Volkmer ◽  
Michael Hirscher
Keyword(s):  
Hydrogen Storage ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Hydrogen Storage Capacity ◽  
Metal Organic

scholarly journals Volumetric Hydrogen Storage Capacity in Metal-Organic Frameworks

2017 ◽  
Vol 6 (3) ◽  
pp. 578-582 ◽  
Author(s):  
R. Balderas-Xicohténcatl ◽  
Maurice Schlichtenmayer ◽  
Michael Hirscher
Keyword(s):  
Hydrogen Storage ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Hydrogen Storage Capacity ◽  
Metal Organic
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