Specific features of “compensating” copolymerization of butyl acrylate with vinyl butyl ether in the presence of triethylboron

2017 ◽  
Vol 66 (9) ◽  
pp. 1660-1664 ◽  
Author(s):  
L. L. Semenycheva ◽  
Yu. O. Matkivskaia ◽  
N. B. Valetova ◽  
Yu. O. Chasova ◽  
N. L. Pegeev ◽  
...  
Keyword(s):  

2009 ◽  
Vol 82 (9) ◽  
pp. 1644-1647 ◽  
Author(s):  
L. L. Semenycheva ◽  
V. V. Vins ◽  
E. I. Bogatova ◽  
E. V. Malysheva ◽  
G. V. Khoroshen’kov ◽  
...  
Keyword(s):  


2016 ◽  
Vol 89 (10) ◽  
pp. 1667-1672
Author(s):  
L. L. Semenycheva ◽  
N. B. Valetova ◽  
A. A. Moikin ◽  
N. L. Pegeev ◽  
Yu. O. Matkivskaya ◽  
...  


Author(s):  
Gudrun A. Hutchins

In order to optimize the toughening effect of elastomers in engineering polymers, it is necessary to characterize the size, morphology and dispersion of the specific elastomer within the polymer matrix. For unsaturated elastomers such as butadiene or isoprene, staining with osmium tetroxide is a well established procedure. The residual carbon-carbon double bond in these materials is the reactive site and forms a 1,2-dilato complex with the OsO4. Incorporation of osmium tetroxide into the elastomer not only produces sufficient contrast for TEM, but also crosslinks the elastomer sufficiently so that ultramicrotomy can be accomplished at room temperature with minimal distortion.Blends containing saturated elastomers such as butyl acrylate (BA) and ethylene propylene diene monomer (EPDM) cannot be stained directly with OsO4 because effective reaction sites such as C=C or -NH2 are not available in sufficient number. If additional reaction sites can be introduced selectively into the elastomer by a chemical reaction or the absorption of a solvent, a modified, two-step osmium staining procedure is possible.









2017 ◽  
pp. 91-95
Author(s):  
E. I. Grushova ◽  
A. .. Al Razuqi ◽  
E. S. Chaiko ◽  
O. A. Miloserdova

IR spectroscopy investigated structural and group composition of base mineral oils isolated from the vacuum distillate by selective purification of N-methylpyrrolidone and the low temperature dewaxing in the presence of a solvent. The role of the latter was carried out by the systems acetone - toluene, acetone - methyl tertiary butyl ether, methyl ethyl ketone - toluene, acetone - toluene - modifying additive. It was shown that the chemical composition of the group of base oils and slack waxes is defined as the nature of the solvent to the dewaxing, and oils sequence of purification steps.



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