molecular mass
Recently Published Documents


TOTAL DOCUMENTS

3918
(FIVE YEARS 284)

H-INDEX

111
(FIVE YEARS 9)

Author(s):  
Anna Ivanova ◽  
Alexey Polotsky ◽  
A. M. Skvortsov ◽  
Leonid Klushin ◽  
Friederike Schmid

2022 ◽  
Vol 2148 (1) ◽  
pp. 012027
Author(s):  
Ting Peng ◽  
Kesheng Yang ◽  
Taoyan Zhou ◽  
Heng Wu

Abstract Styrene Butadiene Styrene (SBS) is widely used in pavements because it significantly improves the performance of the modified asphalt. The dosage of SBS has an important effect on the low-temperature performance of the modified asphalt. The difference in relative molecular weight influences the magnitude of the change in low-temperature performance. In this paper, low temperature bending beams rheology test of five different relative molecular weight SBS modified asphalt is conducted at -12°C, -18°C and -24°C to evaluate the low-temperature properties of modified asphalt. Then, the experimental results are analysed. The results show that there is a certain correlation between the relative molecular mass of SBS and the low-temperature performance of modified asphalt. The creep stiffness and creep rate of the modified asphalt are influenced by the relative molecular mass of SBS and temperature. As the relative molecular mass increases, the low-temperature performance of the modified asphalt first rises and then decreases.


2021 ◽  
Vol 4 (4) ◽  
Author(s):  
E. D. Lodygin ◽  
R. S. Vasilevich

Purpose of the study: to reveal the influence of hydromorphism and agricultural use on the molecular-mass distribution (MMD) of humic (HAs) and fulvic acids (FAs) isolated from the soils of the European northeast of Russia. To assess the influence of the acidity of the medium on the MWD of FAs. Place and time of the event. The studies were carried out on the territory of the middle taiga (Maksimovsky station of the Institute of Biology of the Federal Research Center of the KSC UB RAS, located 8 km west of the city of Syktyvkar and the field of the Syktyvkar state farm, 5 km south-west of Syktyvkar, on the watershed of the Sysola and Vazhel-yu rivers) and northern taiga (3 km west of the Troitsko-Pechorsk station). The objects of the study were humic substances isolated from typical podzolic (Eutric Albic Retisol (Loamic)), gleypodzolic (Eutric Albic Stagnic Retisol (Loamic)), peaty-podzolic surface-gleyed (Eutric Albic Stagnic Histic) Retisol (Loamic Eutric Albic Retisol (Loamic)) soils. The soil sampling period is from 1 to 30 August 2014. Methodology. Quantitative analysis of the MMD of HA and FA preparations was performed using liquid size exclusion chromatography (gel chromatography) on Sephadex G-25 and G-100 gels with continuous automatic registration of the optical density of the eluate (λ = 280 nm) in a quartz flow cell, K 9 × 60 cm column (Pharmacia, Sweden). Distilled water, 0.05 M NaOH solution, and Tris-HCl buffer with pH = 8.2 were used as the eluent. Main results. Studies of the MMD of humic substances have been carried out. It was found that HAs contain three fractions with different molecular weights: ≥ 150 kDa, 73–80 kDa, and 13–23 kDa; FAs – two fractions: ≥ 5 kDa, 1–2 kDa. The low molecular weight of FAs, together with a large amount of oxygen-containing functional groups, contributes to their better solubility and migration ability in soils. The HAs of automorphic soils are characterized by a high content of low molecular weight fractions, and the proportion of the high molecular weight fraction in the HAs of the litter is 1.5–2.0 times higher than in the HAs of the podzolic horizon, which may be due to the migration of the low molecular weight fraction down the profile. The high proportion of the acidic low molecular weight fraction in the podzolic horizon promotes the decomposition of soil minerals and their leaching into the illuvial horizon. The influence of agricultural use of soils on the fractional composition of humic compounds is estimated. A sharp increase in the share of the high molecular weight fraction in the preparations of HAs of arable podzolic soil by 2–4 times compared with the HAs of virgin podzolic soils was noted, which is due to the cultivation of the arable horizon, the nature of the incoming plant residues and the increased microbiological activity of the developed soils. The effect of acidity of the medium on the character of chromatograms of FA preparations isolated from the main types of soils of the Komi Republic was studied. It has been shown that in the region of high pH values of the eluent 9–13, the absence of fractionation is associated with the association of FAs, a change in their conformation, and the effect of “over-exclusion”. Elution with distilled water (pH = 6.5) allows the separation of FAs into two fractions with molecular weights ≥ 5 kDa and 1–2 kDa.


ACS Omega ◽  
2021 ◽  
Author(s):  
Yu Lin Lee ◽  
Daniel W. Lester ◽  
Julian R. Jones ◽  
Theoni K. Georgiou

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7724
Author(s):  
Agnieszka Adamczuk ◽  
Milena Kercheva ◽  
Mariana Hristova ◽  
Grzegorz Jozefaciuk

Chitosan has become increasingly applied in agriculture worldwide, thus entering the soil environment. We hypothesized that chitosan should affect the water stability of soil. Since this problem has not been studied to date, we examined, for the first time, the influence of chitosan on the water stability and wettability of soil aggregates. The aggregates were prepared from four soils with various properties amended with different amounts of two kinds of powdered chitosan, and subjected to 1 and/or 10 wetting–drying cycles. The water stability was measured by monitoring air bubbling after aggregate immersion in water, and the wettability was measured by a water drop penetration test. The biopolymer with a lower molecular mass, lower viscosity, and higher degree of deacetylation was more effective in increasing the water stability of the soil than the biopolymer with a higher molecular mass, higher viscosity, and lower deacetylation degree. After a single wetting-drying cycle, the water stability of the soil aggregates containing chitosan with a higher molecular mass was generally lower than that of the soil; after ten wetting–drying cycles, the water stability increased 1.5 to 20 times depending on the soil. The addition of low-molecular-mass chitosan after a single wetting-drying cycle caused the water stability to become one to two hundred times higher than that of the soil. A trial to find out which soil properties (pH, C and N content, bulk density, porosity, and particle size distribution) are responsible for the effectiveness of chitosan action was not successful, and this will be the objective of further studies.


2021 ◽  
Author(s):  
Alexander H. Mason ◽  
Alessandro Motta ◽  
Anusheela Das ◽  
Qing Ma ◽  
Michael J. Bedzyk ◽  
...  

Polyolefins comprise a major fraction of single-use plastics and yet their catalytic deconstruction/recycling has proven challenging due to their inert hydrocarbon connectivities. Here an electrophilic earth-abundant single-site organozirconium catalyst chemisorbed on a highly Brønsted acidic support and characterized by a broad array of experimental and theoretical techniques, is shown to mediate the rapid hydrogenolytic cleavage of molecular and macromolecular saturated hydrocarbons under mild conditions. For n-hexadecane, hydrogenolysis to light hydrocarbons proceeds with an activity of 690 mol n-hexadecane · mol Zr-1 · h-1 at 150°C/2.5 atm H2 pressure. Under similar solventless conditions, polyethylene, polyethylene-co- 1-octene, isotactic polypropylene, and a post-consumer sandwich bag are rapidly hydrogenolyzed to low molecular mass hydrocarbons via a turnover-limiting C-C scission pathway involving ßalkyl transfer rather than more common σ-bond metathesis.


Sign in / Sign up

Export Citation Format

Share Document