For many industries, further progress is possible provided that more efficient refractories of new types are created.
The refractory concretes bonded by calcium aluminate phosphate binders in comparison with conventional refractories continue to gain in popularity because of the following advantages: quick installation and low construction costs; reduced and simplified furnace maintenance; good thermal-shock resistance; monolithic (no joints); linings of the units done need not be cured to develop initial strength. The longevity of refractory is essentially increasing provided structure is forming under conditions of the service site. That is why developing of new refractory materials must be carried out by means of its structure design. These principles have been realizing in the refractory concretes technology under the limited conditions of refractory lining installation and industrial unit final heat up.
The present paper identifies the phosphate phases responsible for developing mechanical-strength properties of high alumina concretes bonded with calcium aluminate phosphate binders. It sets out the colloid and crystalline phases resulted from interphase interaction that provides the basis for calcium aluminate phosphate binders (suspensions) useful to the refractory industry. The concretes obtained retain their volume integrity after 30 cycles of heating and cooling; can be used for refractory applications > 1700 °С; exhibit sufficient strength of lining 40 MPa.
Study of aluminium oxide from high-alumina refractory ceramics by thermoluminescence
