scholarly journals Synthesis and two-photon absorption property of new π -conjugated donor–acceptor polymers carrying different heteroaromatics

2013 ◽  
Vol 125 (1) ◽  
pp. 29-40 ◽  
Author(s):  
M S SUNITHA ◽  
K A VISHNUMURTHY ◽  
A V ADHIKARI
Keyword(s):  
Photon Absorption ◽  
Absorption Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

Two-Photon Absorption Property of a Conjugated Polymer: Influence of Solvent and Concentration on Its Property

2010 ◽  
Vol 114 (1) ◽  
pp. 22-27 ◽  
Author(s):  
Hongli Wang ◽  
Zhen Li ◽  
Pin Shao ◽  
Jingui Qin ◽  
Zhen-li Huang
Keyword(s):  
Conjugated Polymer ◽  
Photon Absorption ◽  
Absorption Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Influence Of Solvent

scholarly journals Tuning of Hyperpolarizability, One- and Two-Photon Absorption of D-A and D-A-A Type Intramolecular Charge Transfer Based Sensors

2019 ◽  
Author(s):  
Pralok K. Samanta ◽  
Md Mehboob Alam ◽  
Ramprasad Misra ◽  
Swapan K. Pati
Keyword(s):  
Charge Transfer ◽  
Gas Phase ◽  
Density Functional ◽  
Intramolecular Charge Transfer ◽  
Photon Absorption ◽  
First Hyperpolarizability ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Nlo Response ◽  
Donor Acceptor

Solvents play an important role in shaping the intramolecular charge transfer (ICT) properties of π-conjugated molecules, which in turn can affect their one-photon absorption (OPA) and two-photon absorption (TPA) as well as the static (hyper)polarizabilities. Here, we study the effect of solvent and donor-acceptor arrangement on linear and nonlinear optical (NLO) response properties of two novel ICT-based fluorescent sensors, one consisting of hemicyanine and dimethylaniline as electron withdrawing and donating groups (molecule 1), respectively and its boron-dipyrromethene (BODIPY, molecule 2)-fused counterpart (molecule 3). Density functional theoretical (DFT) calculations using long-range corrected CAM-B3LYP and M06-2X functionals, suitable for studying properties of ICT molecules, are employed to calculate the desired properties. The dipole moment (µ) as well as the total first hyperpolarizability (β<sub>total</sub>) of the studied molecules in the gas phase is dominantly dictated by the component in the direction of charge transfer. The ratios of vector component of first hyperpolarizability (β<sub>vec</sub>) to β<sub>total</sub> also reveal unidirectional charge transfer process. The properties of the medium significantly affect the OPA, hyperpolarizability and TPA properties of the studied molecules. Time dependent DFT (TDDFT) calculations suggest interchanging between two lowest excited states of molecule 3 from the gas phase to salvation. The direction of charge polarization and dominant transitions among molecular orbitals involved in the OPA and TPA processes are studied. The results presented are expected to be useful in tuning the NLO response of many ICT-based chromophores, especially those with BODIPY acceptors.<br>

Multiple Intramolecular Charge Transfers in Multimodular Donor–Acceptor Chromophores with Large Two-Photon Absorption

2020 ◽  
Vol 124 (45) ◽  
pp. 24631-24643
Author(s):  
Yogajivan Rout ◽  
Alessio Cesaretti ◽  
Elena Ferraguzzi ◽  
Benedetta Carlotti ◽  
Rajneesh Misra
Keyword(s):  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

Strategy towards large two-photon absorption cross-sections for diketopyrrolopyrroles

2015 ◽  
Vol 3 (4) ◽  
pp. 742-749 ◽  
Author(s):  
Anna Purc ◽  
Krzysztof Sobczyk ◽  
Yusuke Sakagami ◽  
Akihiro Ando ◽  
Kenji Kamada ◽  
...  
Keyword(s):  
Cross Sections ◽  
Photon Absorption ◽  
Absorption Cross ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

Decorating diketopyrrolopyrroles with strongly electron-rich heterocycles led to donor–acceptor–donor architectures possessing two-photon brightness 850–1900 GM.

scholarly journals Two-photon absorption and spectroscopy of the lowest two-photon transition in small donor-acceptor–substituted organic molecules

2015 ◽  
Vol 91 (4) ◽  
Author(s):  
Marten T. Beels ◽  
Ivan Biaggio ◽  
Tristan Reekie ◽  
Melanie Chiu ◽  
François Diederich
Keyword(s):  
Organic Molecules ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Photon Transition ◽  
Donor Acceptor

Two-photon absorption property of Cl-substituted diphenylacetylenes by optical-probing photoacoustic spectroscopy

2019 ◽  
Vol 151 (13) ◽  
pp. 134304
Author(s):  
Tetsuro Ishii ◽  
Saki Ando ◽  
Tasuku Isozaki ◽  
Ryo Takeuchi ◽  
Wataru Kashihara ◽  
...  
Keyword(s):  
Photoacoustic Spectroscopy ◽  
Photon Absorption ◽  
Absorption Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Optical Probing

Extremely Efficient Two-Photon Absorption in Small Donor-Acceptor Substituted Organic Molecules

2015 ◽  
Author(s):  
M. T. Beels ◽  
I. Biaggio ◽  
T. Reekie ◽  
M. Chiu ◽  
F. Diederich
Keyword(s):  
Organic Molecules ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

Synthesis and two-photon absorption property of novel salen complexes incorporated with two pendant azo dyes

2009 ◽  
Vol 50 (13) ◽  
pp. 1371-1373 ◽  
Author(s):  
Zihong Ye ◽  
Leonardo De Boni ◽  
Ubaldo Martins Neves ◽  
C.R. Mendonça ◽  
Xiu R. Bu
Keyword(s):  
Azo Dyes ◽  
Photon Absorption ◽  
Absorption Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Salen Complexes

Mechanisms for enhancement of two-photon absorption in donor–acceptor conjugated chromophores

1998 ◽  
Vol 298 (1-3) ◽  
pp. 1-6 ◽  
Author(s):  
T. Kogej ◽  
D. Beljonne ◽  
F. Meyers ◽  
J.W. Perry ◽  
S.R. Marder ◽  
...  
Keyword(s):  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

Preparation and Photophysical Properties of All-trans Acceptor–π-Donor (Acceptor) Compounds Possessing Obvious Solvatochromic Effects

2017 ◽  
Vol 70 (9) ◽  
pp. 1048
Author(s):  
Yu-Lu Pan ◽  
Zhi-Bin Cai ◽  
Li Bai ◽  
Sheng-Li Li ◽  
Yu-Peng Tian
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Photophysical Properties ◽  
Emission Spectra ◽  
Photon Absorption ◽  
Linear Absorption ◽  
Functional Theory ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Donor Acceptor

A series of all-trans acceptor–π-donor (acceptor) compounds (BAQ, SFQ, BLQ, and XJQ) were conveniently synthesised and characterised by infrared, nuclear magnetic resonance, mass spectrometry, and elemental analysis. Their photophysical properties, including linear absorption, one-photon excited fluorescence, two-photon absorption, and two-photon excited fluorescence, were systematically investigated. All the compounds show obvious solvatochromic effects, such as significant bathochromic shifts of the emission spectra and larger Stokes shifts in more polar solvents. Under excitation from a femtosecond Ti : sapphire laser with a pulse width of 140 fs, they all exhibit strong two-photon excited fluorescence, and the two-photon absorption cross-sections in THF are 851 (BAQ), 216 (SFQ), 561 (BLQ), and 447 (XJQ) GM respectively. A combination of density functional theory (DFT) and time-dependent density functional theory (TDDFT) approaches was used to investigate the relationships between the structures and the photophysical properties of these compounds. The results show that they may have a potential application as polarity-sensitive two-photon fluorescent probes.

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