Preparation of Ni-La/Al2O3-CeO2-Bamboo Charcoal Catalyst and Its Application in Co-pyrolysis of Straw and Plastic for Hydrogen Production

Abstract The developed Ni-La/Al2O3-CeO2-Bamboo charcoal (ACB) catalyst was applied to the co-pyrolysis of straw and plastic to produce hydrogen in a horizontal quartz tube pyrolysis furnace. In this study, the effects of the mixing ratio of straw and plastic, the presence and stability of the catalyst on the co-pyrolysis hydrogen production were investigated. Experiment showed that the addition of PE can increase the yield of H2 within a certain range, and the best mass ratio of 5:5 was found. In the co-pyrolysis process with the participation of the catalysts, the macromolecular tar can be cracked into combustible gases such as H2, and the H2 yield could be increased to 332.2ml/g (Ni-La/ACB) is much higher than 68.87ml/g without catalyst. Compared with Ni/ACB, Ni-La/ACB had been increased the alkalinity by adding La element and enhanced the carbon deposition resistance of the catalyst, which makes the catalyst maintain higher stability. This was also confirmed in stability test experiments.

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Development of bamboo charcoal and fragaria vesca powder photocatalysts in hydrogen production via water splitting

Eastern-European Journal of Enterprise Technologies ◽

10.15587/1729-4061.2020.213277 ◽

2020 ◽

Vol 6 (6 (108)) ◽

pp. 80-92

Author(s):

Yepy Komaril Sofi’i ◽

Eko Siswanto ◽

Winarto Winarto ◽

I Nyoman Gede Wardana

Keyword(s):

Hydrogen Production ◽

Water Splitting ◽

Fragaria Vesca ◽

Bamboo Charcoal

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Hydrogen Production, Separation and Purification for Energy

10.1049/pbpo089e ◽

2017 ◽

Cited By ~ 2

Keyword(s):

Hydrogen Production ◽

Separation And Purification

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Utilization of electrical charges in the pores of tofu waste for hydrogen production in water

WEENTECH Proceedings in Energy ◽

10.32438/wpe.1720 ◽

2020 ◽

pp. 124-135

Author(s):

I. N. G. Wardana ◽

N. Willy Satrio

Keyword(s):

Magnetic Field ◽

Hydrogen Production ◽

Sodium Bicarbonate ◽

Positive Charge ◽

Electrical Energy ◽

Hydrogen Sensor ◽

Water Molecules ◽

Partial Charge ◽

Delocalized Electron ◽

Water Hydrogen

Tofu is main food in Indonesia and its waste generally pollutes the waters. This study aims to change the waste into energy by utilizing the electric charge in the pores of tofu waste to produce hydrogen in water. The tofu pore is negatively charged and the surface surrounding the pore has a positive charge. The positive and negative electric charges stretch water molecules that have a partial charge. With the addition of a 12V electrical energy during electrolysis, water breaks down into hydrogen. The test was conducted on pre-treated tofu waste suspension using oxalic acid. The hydrogen concentration was measured by a MQ-8 hydrogen sensor. The result shows that the addition of turmeric together with sodium bicarbonate to tofu waste in water, hydrogen production increased more than four times. This is due to the fact that magnetic field generated by delocalized electron in aromatic ring in turmeric energizes all electrons in the pores of tofu waste, in the sodium bicarbonate, and in water that boosts hydrogen production. At the same time the stronger partial charge in natrium bicarbonate shields the hydrogen proton from strong attraction of tofu pores. These two combined effect are very powerful for larger hydrogen production in water by tofu waste.

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