Synthesis and characterization of a novel charring agent and its application in intumescent flame retardant polyethylene system

In this study, a novel phosphorus-nitrogen containing intumescent flame retardant (P-N IFR) poly(melamine 2-carboxyethyl(phenyl) phosphate)(PMCEP) was prepared via the reaction of 2-carboxyethyl (phenyl) phosphinic acid (CEPPA) and melamine (MEL) in two-steps. Meanwhile, the molecular structure of the chemical compound was determined by FTIR,1H-NMR and elemental analysis; and the thermal properties was investigated by means of TGA. Combustion studies revealed high limiting oxygen index (LOI) indicative of better flame-retardancy properties for PBT resin.

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Synthesis and Characterization of Triazine-Based Charring Agent and its Application in Flame Retarded Polypropylene

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1033-1034.623 ◽

2014 ◽

Vol 1033-1034 ◽

pp. 623-626

Author(s):

Ning Ping Wang ◽

Hai Shan Tang ◽

Lang Ping Xia ◽

Si Chun Shao ◽

Jie Zhu ◽

...

Keyword(s):

Fourier Transform ◽

Infrared Spectroscopy ◽

Flame Retardant ◽

Synthesis And Characterization ◽

Fire Retardancy ◽

Chemical Structures ◽

Charring Agent ◽

Flame Retarded ◽

Ft Ir

In this study, N,N-(2,4-diamino-1,3,5-triazinyl) diethylenetriamine were synthesized by cyanuric chloride, diethylenetriamine and ammonia with a novel process in three steps, and it can be used as charring agent in intumescent flame retardant. Its chemical structures were characterized by Fourier-transform infrared spectroscopy (FT-IR) and elemental analysis. Meanwhile, the TGA results showed that triazine-based charring agent had good thermostability. Furthermore, the fire performancce of composites blended by the flame retardant and polypropylene was investigated by vertical burning test. The results revealed good fire retardancy that flame retardant polypropylene with 5.1wt% charring agent, 2.8wt% anti-dripping and 20.1wt% APP, was reached UL-94 V-0 rating.

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Synthesis and characterization of NaA zeolite particle as intumescent flame retardant in chloroprene rubber system

Particuology ◽

10.1016/j.partic.2010.05.016 ◽

2011 ◽

Vol 9 (3) ◽

pp. 248-252 ◽

Cited By ~ 11

Author(s):

Wenhui Yuan ◽

Huarong Chen ◽

Ranran Chang ◽

Li Li

Keyword(s):

Flame Retardant ◽

Intumescent Flame Retardant ◽

Synthesis And Characterization ◽

Naa Zeolite ◽

Zeolite Particle ◽

Chloroprene Rubber

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Synthesis and characterization of bio‐based intumescent flame retardant and its application in polyurethane

Fire and Materials ◽

10.1002/fam.2877 ◽

2020 ◽

Vol 44 (6) ◽

pp. 814-824

Author(s):

Yalin Xing ◽

YanQiu Li ◽

Zhaojun Lin ◽

Xiao Ma ◽

Hao Qu ◽

...

Keyword(s):

Flame Retardant ◽

Intumescent Flame Retardant ◽

Synthesis And Characterization

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Preparation and characterization of polydopamine/melamine microencapsulated red phosphorus and its flame retardance in epoxy resin

RSC Advances ◽

10.1039/d1ra03164c ◽

2021 ◽

Vol 11 (33) ◽

pp. 20391-20402

Author(s):

Chen Cheng ◽

Yanling Lu ◽

Weining Ma ◽

Shaojie Li ◽

Jun Yan ◽

...

Keyword(s):

Flame Retardant ◽

Epoxy Resin ◽

Shell Structure ◽

Composite Shell ◽

Intumescent Flame Retardant ◽

Smoke Suppression ◽

Flame Retardance ◽

Red Phosphorus ◽

Composite Shell Structure

Red phosphorus was coated by a polydopamine/melamine composite shell structure, which constituted an intumescent flame retardant with superior flame retardance and smoke suppression performance for epoxy resin.

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Synthesis and characterization of PEDMCD as a flame retardant and its application in epoxy resins

RSC Advances ◽

10.1039/d0ra10233d ◽

2021 ◽

Vol 11 (5) ◽

pp. 2756-2766

Author(s):

Yi Zhang ◽

Weiwei Yang

Keyword(s):

Flame Retardant ◽

Epoxy Resins ◽

Synthesis And Characterization ◽

Direct Polycondensation ◽

Polycondensation Reaction ◽

Highly Effective

In this study, a highly effective flame retardant agent, called polybicyclopentaerythritol phosphate-O-4-imino-p-phenylmethane-4-imino-2-chloro-1,3,5-s-triazine (PEDMCD), has been prepared through a direct polycondensation reaction.

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