Metal organic frameworks as emergent oxygen-reducing cathode catalysts for microbial fuel cells: a review

Author(s):  
M. Priyadarshini ◽  
A. Ahmad ◽  
S. Das ◽  
M. M. Ghangrekar
2020 ◽  
Vol 450 ◽  
pp. 227681 ◽  
Author(s):  
Yan Wang ◽  
Kengqiang Zhong ◽  
Zhongyi Huang ◽  
Leyi Chen ◽  
Yi Dai ◽  
...  

2014 ◽  
Vol 70 (10) ◽  
pp. 1610-1616 ◽  
Author(s):  
Huanan Wu ◽  
Min Lu ◽  
Lin Guo ◽  
Leonard Guan Hong Bay ◽  
Zheng Zhang ◽  
...  

Polyelectrolyte–single wall carbon nanotube (SCNT) composites are prepared by a solution-based method and used as metal-free cathode catalysts for oxygen reduction reaction (ORR) in air-cathode microbial fuel cells (MFCs). In this study, two types of polyelectrolytes, polydiallyldimethylammonium chloride (PDDA) and poly[bis(2-chloroethyl)ether-alt-1,3-bis[3-(dimethylamino)propyl]urea] (PEPU) are applied to decorate the SCNTs and the resulting catalysts exhibit remarkable catalytic ability toward ORR in MFC applications. The enhanced catalytic ability could be attributed to the positively charged quaternary ammonium sites of polyelectrolytes, which increase the oxygen affinity of SCNTs and reduce activation energy in the oxygen reduction process. It is also found that PEPU–SCNT composite-based MFCs show efficient performance with maximum power density of 270.1 mW m−2, comparable to MFCs with the benchmark Pt/C catalyst (375.3 mW m−2), while PDDA–SCNT composite-based MFCs produce 188.9 mW m−2. These results indicate that PEPU–SCNT and PDDA–SCNT catalysts are promising candidates as metal-free cathode catalysts for ORR in MFCs and could facilitate MFC scaling up and commercialization.


Author(s):  
Srikanth Ponnada ◽  
Maryam Sadat Kiai ◽  
Demudu Babu Gorle ◽  
Annapurna Nowduri ◽  
Rakesh K. Sharma

Author(s):  
Mohammad A. Abdelkareem ◽  
Mohammed Al-Murisi ◽  
Khaled Elsaid ◽  
Enas T. Sayed ◽  
Sameer Al-Asheh ◽  
...  

2020 ◽  
Vol 49 (47) ◽  
pp. 17130-17139
Author(s):  
Lu Feng ◽  
Hao-Bo Hou ◽  
Hong Zhou

As newly emerging proton-conducting materials, metal–organic frameworks (MOFs) have been attracting wide attention in the field of proton exchange membrane fuel cells.


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