The strain energy of a spheroidal inclusion and its application to b.c.c.-h.c.p. martensitic transformation

1975 ◽  
Vol 23 (5) ◽  
pp. 587-597 ◽  
Author(s):  
M. Shibata ◽  
Kanji Ono
2020 ◽  
Vol 321 ◽  
pp. 11009
Author(s):  
M. Morinaga ◽  
H. Yukawa ◽  
M. Yoshino

Local strain is introduced into the lattice around solute atom due to the size mismatch between solute and solvent atoms in alloy. In this study, local lattice strains are calculated for the first time in titanium alloys, using the plane-wave pseudopotential method. As an extreme case, the local lattice strain around a vacancy is also calculated in various bcc, fcc and hcp metals. It is found that the local strain energy is very high in both bcc Ti and bcc Fe, where the martensitic transformation takes place. From a series of calculations, it is shown that the magnitude of the strain energy stored in the local lattice is comparable to the thermal energy, kBT, where kB is the Boltzmann constant and T is the absolute temperature. Therefore, the presence of local lattice strains in alloy could influence the phase stability that varies largely depending on temperatures. For example, the local lattice strain correlates with the martensitic transformation start temperature, Ms, in binary titanium alloys.


Author(s):  
R-R. Lee

Partially-stabilized ZrO2 (PSZ) ceramics have considerable potential for advanced structural applications because of their high strength and toughness. These properties derive from small tetragonal ZrO2 (t-ZrO2) precipitates in a cubic (c) ZrO2 matrix, which transform martensitically to monoclinic (m) symmetry under applied stresses. The kinetics of the martensitic transformation is believed to be nucleation controlled and the nucleation is always stress induced. In situ observation of the martensitic transformation using transmission electron microscopy provides considerable information about the nucleation and growth aspects of the transformation.


Author(s):  
S.R. Summerfelt ◽  
C.B. Carter

The wustite-spinel interface can be viewed as a model interface because the wustite and spinel can share a common f.c.c. oxygen sublattice such that only the cations distribution changes on crossing the interface. In this study, the interface has been formed by a solid state reaction involving either external or internal oxidation. In systems with very small lattice misfit, very large particles (>lμm) with coherent interfaces have been observed. Previously, the wustite-spinel interface had been observed to facet on {111} planes for MgFe2C4 and along {100} planes for MgAl2C4 and MgCr2O4, the spinel then grows preferentially in the <001> direction. Reasons for these experimental observations have been discussed by Henriksen and Kingery by considering the strain energy. The point-defect chemistry of such solid state reactions has been examined by Schmalzried. Although MgO has been the principal matrix material examined, others such as NiO have also been studied.


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