A critical comparison of mercury porosimetry and capillary condensation pore size distributions of portland cement paste A reply to the discussion by James J. Beaudoin

1972 ◽  
Vol 2 (1) ◽  
pp. 148-151 ◽  
Author(s):  
Sidney Diamond
1985 ◽  
Vol 65 ◽  
Author(s):  
Amitabha Kumar ◽  
Della M. Roy

ABSTRACTEffective coefficients for the diffusion of Cs+ and Cl− ions accross hardened plates of Portland cement and Portland cement-fly ash blend pastes were measured at 27°, 38° and 60° for samples cured up to 28 d. The porosity and pore size distributions of the same hardened plates were also determined. The fly ash blends show lower anion and cation diffusion rates at higher temperatures, although the porosity is not significantly different from the neat paste. The finer pore size is considered responsible for the slower diffusion in the blends. The electronegative nature of the pore surfaces also contributes to the slower cation diffusion.


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