Effect of Nano-SiO2 on the Microstructure and Mechanical Properties of Concrete under High Temperature Conditions

The aim of the research was to determine how the admixture of nanosilica affects the structure and mechanical performance of cement concrete exposed to high temperatures (200, 400, 600, and 800 °C). The structural tests were carried out on the cement paste and concrete using the methods of thermogravimetric analysis, mercury porosimetry, and scanning electron microscopy. The results show that despite the growth of the cement matrix’s total porosity with an increasing amount of nanosilica, the resistance to high temperature improves. Such behavior is the result of not only the thermal characteristics of nanosilica itself but also of the porosity structure in the cement matrix and using the effective method of dispersing the nanostructures in concrete. The nanosilica densifies the structure of the concrete, limiting the number of the pores with diameters from 0.3 to 300 μm, which leads to limitation of the microcracks, particularly in the coarse aggregate-cement matrix contact zone. This phenomenon, in turn, diminishes the cracking of the specimens containing nanosilica at high temperatures and improves the mechanical strength.

The Effect of Expanded and Natural Flake Graphite Additives on Positive Active Mass Utilization of the Lead-Acid Battery

The effects of expanded and not expanded (natural flake) graphite additives were evaluated on the discharge utilization of the positive active material (PAM) in the lead-acid battery. Graphite powders were added to the paste at 2.20 vol. % and tested in model 2V battery cells under a wide range of discharge currents from 8C to C/20. The effects of graphite on the PAM pore volume and pore size distribution were measured with mercury porosimetry, and a good correlation was found between the pore volume of the PAM and utilization performance of the cells. It was shown that the powder characteristics of graphite can affect the PAM pore volume. A correlation was found between the graphite additives’ structural order and PAM utilization.

Assessment of the Impact of Modification of Calcium Sorbents and the Possibility of Their Use in Desulfurization for Oxy-Fuel Combustion Process

The paper describes the possibilities of simple and effective modification of calcium sorbents used for flue gas desulfurization with a size between of 125–250 µm. The additives to the sorbents in the amount of 0.5% and 1.0% were inorganic sodium and lithium compounds. The research on the reactivity of sorbents was analyzed in the process of simultaneous calcination and sulfation at the temperature of 850 °C. The type of Na+ or Li+ cations and the inorganic salt anions have an influence on the modification of calcium sorbents in order to improve the efficiency of the calcination and sulfation process. Modification of calcium sorbents by adding inorganic sodium and lithium compounds, regardless of the amount, changes the reactivity coefficient RI [mol/mol] and the absolute sorption coefficient CI [g S/kg sorbent]. In the case of inorganic sodium salt (Additive 1), regardless of the amount of modifier added, there was a visible improvement in the reactivity of the sorbent: 1.0% of the additive caused an increase in the RI coefficient in relation to the raw sorbent by over 14%, and in the case of the CI coefficient by over 24%. Additional research was the analysis of the limestone behavior mechanism during the simultaneous calcination and sulfation (SCS) process under conditions of elevated temperature and with variable CO2 and O2 contents in the flue gas. The behavior of sorbents with a size distribution of 125–250 µm was assessed on the basis of the change in mass of the samples by determining the reactivity coefficient RI, [mol/mol] and the absolute sorption coefficient CI, [g S/kg sorbent]. Using the mercury porosimetry technique, the change in sorbent porosity in the subsequent stages of the simultaneous calcination and sulfation process was investigated. The process was carried out in the temperature range corresponding to the oxy-combustion (i.e., from 850 °C to 1000 °C).

3D Printing Mudrocks: Experiments in Validating Clay as a Build Material for 3D Printing Porous Micromodels

3D printing technologies have the ability to turn digital 3D designs into tangible, lab-testable objects. While 3D printing in plastic and granular materials is quite common now, new equipment has been developed that can 3D print using paste-like materials (e.g., clays, Portland cement, foods). This study characterized simple, core-plug-sized models to evaluate whether this technology can be applied to producing 3D printed analogs for mudrocks. Most models produced were designed as solid, 25-mm-diameter cylinders, 25 mm tall in two different types of clay (Limoges Clay and ISU Clay). Models were printed on a Delta WASP 60100 with the Delta WASP low-density material extruder kit. Models displayed negligible dimensional loss after desiccation but shrank considerably after first firing (8 to 12% loss for both height and diameter). Mass loss was 8 to 11% after the first firing. A second firing yielded 5 to 6% loss for height and diameter, 0.1 to 0.2% mass loss. Models produced from Limoges Clay reduced from ~39% porosity after desiccation to ~7% after first firing to ~1% after the second firing. ISU Clay reduced its porosity less with firing going from ~36 to ~23 to ~10%. Models survived mercury porosimetry up to 33,000 psi (~230 MPa) with no signs of deformation. Pore-throat-size distributions became more monomodal after each firing. For Limoges Clay, the modal pore-throat size lessened after each firing reaching functionally zero after the second firing. ISU Clay’s modal pore-throat size increased after the first firing, before reducing after second firing—though not down to the modal sizes of the desiccated sample. Pore-throat-size distributions were similar to those reported for tight sandstones and shales, suggesting that the method outlined in this study could be used to create analogous pore structures for laboratory experiments with the caveat that surface physics (e.g., wettability) of the models would need to be assessed to understand to what extent it reproduces the properties of natural rock surfaces.

Thermal Conductivity of Sand-Lime Products Modified with Foam Glass Granulate

Waste glass constitutes a significant part of general waste worldwide. Unfortunately, only a small percentage is recycled. It is, therefore, quite important that it can be applied in the production of construction materials. The main aim of this article is to determine the thermal conductivity of the products modified with granulated foam glass (GFG) (recycled product) of the 0.25–0.5 mm fraction, as well as to indicate dependence of the change in volume density of samples caused by the use of GFG and the change of the thermal conductivity coefficient compared to reference samples. For the purpose of this research, various parameters were examined i.a. volume density, water absorption, determination of the pore size distribution by mercury porosimetry and determination of the heat conduction coefficient with the use of a plate apparatus. The test results were developed on the basis of a mathematical model that determined the influence of the filler on the functional properties of the product. The research has shown that the use of GFG in the sand-lime products will contribute to lowering their thermal conductivity by more than 50% compared to traditional products.

Synthesis of Porous Biomimetic Composites: A Sea Urchin Skeleton Used as a Template

The paper presents an original method for the template synthesis of biomimetic porous composites using polyferrophenylsiloxane (PFPS) and the skeleton of the sea urchin Strongylocentrotus intermedius as a structuring template. The study aimed to form an organosilicon base of a composite with an inverted structure relative to the original structure of the sea urchin shell with a period of structure movement of about 20 µm and ceramic composites fabrication with the silicate base with an average pore size distribution of about 10 μm obtained by the reaction of PFPS with the inorganic base of the sea urchin test under conditions of calcination at 1000 °C followed by acid etching. The composition and morphology of the obtained composites were investigated by IR, XRD, XPS, EDX, and SEM techniques and by mercury porosimetry; the parameters of the porous structures depend on the selected methods of their synthesis. The proposed method is of fundamental importance for developing methods for the chemical synthesis of new biomimetics with a unique porosity architecture based on environmentally friendly natural raw materials for a vast practical application.

Use of Computed Tomography Scan Technology to Explore the Porosity of Concrete: Scientific Possibilities and Technological Limitations

This paper shows the scientific possibilities of computed tomography for the study of concrete porosity. The enormous technological advances in computed tomography equipment used in materials research, with increasingly higher energy, better resolution and smaller pixel size will allow, in the near future, viewing pore sizes that are currently unthinkable, competing in resolution with the traditional techniques of mercury porosimetry and nitrogen adsorption. The challenge at that time (and to a lesser extent today) will be how to extract as much information as possible from the large amount of data provided by computed tomography equipment. In this article, through the study of six cubic specimens of 40 mm sides, different techniques of extraction and presentation of the information are shown, which help us to better understand the characterization of the morphology and distribution of the pores inside the concrete matrix. This information is essential to understand some of the macroscopic responses of the concrete.

Multiscale Assessment of Caprock Integrity for Geologic Carbon Storage in the Pennsylvanian Farnsworth Unit, Texas, USA

Leakage pathways through caprock lithologies for underground storage of CO2 and/or enhanced oil recovery (EOR) include intrusion into nano-pore mudstones, flow within fractures and faults, and larger-scale sedimentary heterogeneity (e.g., stacked channel deposits). To assess multiscale sealing integrity of the caprock system that overlies the Morrow B sandstone reservoir, Farnsworth Unit (FWU), Texas, USA, we combine pore-to-core observations, laboratory testing, well logging results, and noble gas analysis. A cluster analysis combining gamma ray, compressional slowness, and other logs was combined with caliper responses and triaxial rock mechanics testing to define eleven lithologic classes across the upper Morrow shale and Thirteen Finger limestone caprock units, with estimations of dynamic elastic moduli and fracture breakdown pressures (minimum horizontal stress gradients) for each class. Mercury porosimetry determinations of CO2 column heights in sealing formations yield values exceeding reservoir height. Noble gas profiles provide a “geologic time-integrated” assessment of fluid flow across the reservoir-caprock system, with Morrow B reservoir measurements consistent with decades-long EOR water-flooding, and upper Morrow shale and lower Thirteen Finger limestone values being consistent with long-term geohydrologic isolation. Together, these data suggest an excellent sealing capacity for the FWU and provide limits for injection pressure increases accompanying carbon storage activities.

Porous Composite Granules with Potential Function of Bone Substitute and Simvastatin Releasing System: A Preliminary Study

In this work, 3D porous granules based on Zn and Se-containing calcium phosphates (CaPs) were fabricated using a droplet-extrusion technique. The composite beads varied in composition and contained two different natural polymers: sodium alginate (SA) and gelatin (GEL). To analyse and compare their physicochemical properties, such as porosity and morphology, different techniques were applied, including scanning electron microscopy (SEM), sorption of N2 and mercury porosimetry. Prior to the fabrication of the granules, the properties of CaPs materials, (the bioceramic base of the beads), selenium (IV)-substituted hydroxyapatite (Se-HA) and zinc-substituted dicalcium phosphate dihydrate (Zn-DCPD), were also investigated. The results of cell viability assessment showed that Se-HA powder was non-toxic to human osteoblasts (hFOB 1.19) and simultaneously exhibited high toxicity to tumour cells (Saos-2). Once the cytotoxicity assay was completed, Se-HA and Zn-DCPD were used to prepare 3D materials. The prepared porous granules were used as matrices to deliver simvastatin to bones. Simvastatin was applied in either the lipophilic form or hydrophilic form. The release kinetics of simvastatin from granules of different composition was then assessed and compared.

Study on Concrete Deterioration in Different NaCl-Na2SO4 Solutions and the Mechanism of Cl− Diffusion

The diffusion of sulfate (SO42−) and chloride (Cl−) ions from rivers, salt lakes and saline soil into reinforced concrete is one of the main factors that contributes to the corrosion of steel reinforcing bars, thus reducing their mechanical properties. This work experimentally investigated the corrosion process involving various concentrations of NaCl-Na2SO4 leading to the coupled erosion of concrete. The appearance, weight, and mechanical properties of the concrete were measured throughout the erosion process, and the Cl− and SO42− contents in concrete were determined using Cl− rapid testing and spectrophotometry, respectively. Scanning electron microscopy, energy spectrometry, X-ray diffractometry, and mercury porosimetry were also employed to analyze microstructural changes and complex mineral combinations in these samples. The results showed that with higher Na2SO4 concentration and longer exposure time, the mass, compressive strength, and relative dynamic elastic modulus gradually increased and large pores gradually transitioned to medium and small pores. When the Na2SO4 mass fraction in the salt solution was ≥10 wt%, there was a downward trend in the mechanical properties after exposure for a certain period of time. The Cl− diffusion rate was thus related to Na2SO4 concentration. When the Na2SO4 mass fraction in solution was ≤5 wt% and exposure time short, SO42− and cement hydration/corrosion products hindered Cl− migration. In a concentrated Na2SO4 environment (≥10 wt%), the Cl− diffusion rate was accelerated in the later stages of exposure. These experiments further revealed that the Cl− migration rate was higher than that of SO42−.