Homogeneous nucleation at high pressures in some aqueous solutions of cryoprotectant interest

Cryobiology ◽  
1988 ◽  
Vol 25 (6) ◽  
pp. 539-540
Author(s):  
M. Forsyth ◽  
D.R. MacFarlane
CrystEngComm ◽  
2019 ◽  
Vol 21 (48) ◽  
pp. 7507-7518 ◽  
Author(s):  
Soroush Ahmadi ◽  
Yuanyi Wu ◽  
Sohrab Rohani

Molecular dynamics (MD) simulation is used to investigate the mechanism of crystal nucleation of potassium chloride (KCl) in a supersaturated aqueous solution at 293 K and 1 atm.


1967 ◽  
Vol 46 (8) ◽  
pp. 2995-3000 ◽  
Author(s):  
Robert R. Hentz ◽  
Farhataziz ◽  
David J. Milner ◽  
Milton Burton

1988 ◽  
Vol 9 (4) ◽  
pp. 511-523 ◽  
Author(s):  
Y. Tanaka ◽  
K. Ohta ◽  
H. Kubota ◽  
T. Makita

2015 ◽  
Vol 393 ◽  
pp. 33-39 ◽  
Author(s):  
Negar Sadegh ◽  
Kaj Thomsen ◽  
Even Solbraa ◽  
Eivind Johannessen ◽  
Gunn Iren Rudolfsen ◽  
...  

The principal aim of this paper was to test the nearness of possible approach to complete osmotic efficiency for strong solutions. To this end the experimental verification of the exact physical equation given by A. W. Porter was undertaken, a membrane having been constructed which could withstand osmotic pressures of calcium ferrocyanide up to 150 atmospheres without any sensible percolation of the solution. It was found, notwithstanding many precautions, that the formula would not verify within about 3 per cent. But further consideration showed that this formula must refer to osmotic pressures in vacuo , whereas the experiments were necessarily conducted in air at atmospheric pressure. Reconstructing the argument in terms of ideal osmotic partitions impermeable to air but permeable to the solution, the equation was modified so as to apply strictly to the quantities involved in the experimental determinations, which required the addition of the atmospheric pressure to the limits in the first and third of the integrals concerned in it. From the concordance of these numbers, it may fairly be deduced that the membrane establishes, unambiguously, even with concentrated solutions, the full theoretical osmotic pressures, for the thermodynamic relations, at these high pressures, are completely verified.


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