Infrared photochemistry of weak and medium strength hydrogen-bonded complexes, involving HI as proton donor, trapped in inert matrices

1990 ◽  
Vol 222 (1-2) ◽  
pp. 141-149 ◽  
Author(s):  
L. Schriver ◽  
A. Schriver ◽  
J.-P. Perchard
1989 ◽  
Vol 135 (2) ◽  
pp. 285-299 ◽  
Author(s):  
Y. Hannachi ◽  
L. Schriver ◽  
A. Schriver ◽  
J.P. Perchard

Author(s):  
A. Aathif Basha ◽  
F. Liakath Ali Khan

At 308 K, using a 9.37 GHz dielectric relaxation setup, dielectric studies of hydrogen bonded complexes of benzamide and acetamide with 4-fluorophenol, 4-bromophenol, 4-chlorophenol, and 4-iodophenol in benzene were performed. Various dielectric parameters (such as ??, ??, ?0, and ??) were tested. The steric interactions of the proton donor determined the group rotation relaxation time t(2), whereas the significance of Higasi’s single frequency method for multiple relaxation time t(1) was determined by the hydrogen bonding power of the phenolic hydrogen. The presence of a 1:1 complex system between the prepared samples, as well as a charge transfer between the free hydroxyl group of phenols and the carbonyl group of amides was confirmed by the fact that the relaxation time and molar free energy activation of the 1:1 molar ratio were greater than some other higher molar ratios (i.e. 3:1, 2:1, 1:2, 1:3).


1990 ◽  
Author(s):  
L. Schriver ◽  
A. Schriver ◽  
S. Racine ◽  
J. P. Perchard

2015 ◽  
Vol 119 (51) ◽  
pp. 12656-12664 ◽  
Author(s):  
Kanupriya Verma ◽  
Kapil Dave ◽  
K. S. Viswanathan

2021 ◽  
Author(s):  
Thufail M. Ismail ◽  
Neetha Mohan ◽  
P. K. Sajith

Interaction energy (Eint) of hydrogen bonded complexes of nitroxide radicals can be assessed in terms of the deepest minimum of molecular electrostatic potential (Vmin).


2021 ◽  
pp. 2100097
Author(s):  
Aliaksei Aliakseyeu ◽  
Elena E. Dormidontova ◽  
Svetlana A. Sukhishvili

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