Abstract
The major obstacle prohibiting the practical application of Sn-based anodes is drastic volume variation during cycling processes. Here, polyacrylonitrile (PAN) was acted as carbon source, stannic chloride pentahydrate (SnCl4.5H2O) and antimony chloride (SbCl3) were used as SnSb precursors. SnSb/C nanofibers were prepared via simple electrospinning, deep cryogenic treatment, and carbonization, its applied in anode materials for Lithium ion Batteries (LIBs) to achieve excellent cycle performance(115.5% capacity retention for 100 cycles). The improvement of electrochemical performance is mainly attributed to the synergistic effect of deep cryogenic treated special SnSb/C nanofibers precursor. In the deep cryogenic treatment process, the crystalline water in the precursor has a pore forming effect, the porous nanofiber structure leads to the phenomenon of capacity increase. The above results indicate that comprehensive consideration of deep cryogenic treatment and nanofiber precursors is a new idea to enhance the electrochemical performance of LIBs anode materials.