Reactivity of mono- and di-methoxycarbonyl complexes of PdII towards amines and copper amine complexes: role of copper in the catalyzed palladium-copper oxidative carbonylation of amines

1994 ◽  
Vol 470 (1-2) ◽  
pp. 249-252 ◽  
Author(s):  
Potenzo Giannoccaro
Keyword(s):  
Oxidative Carbonylation ◽  
Amine Complexes ◽  
Copper Amine

scholarly journals Resistance to Growth of Molds for Wood Modified with Hydrophobic Hybrid Silica Gel Containing Copper Amine Complexes

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 577
Author(s):  
Shaokun Hao ◽  
Chuanshuang Hu ◽  
Xiuyi Lin ◽  
Jin Gu ◽  
Hong Yun ◽  
...  
Keyword(s):  
Silica Gel ◽  
High Efficiency ◽  
Copper Chloride ◽  
Sol Gel ◽  
Untreated Wood ◽  
Populus Tomentosa ◽  
Amine Complexes ◽  
Hybrid Silica ◽  
Sol Gel Process ◽  
Copper Amine

Complexation copper with amine provides an effective strategy for fixation copper in wood, while hydrophobic modification improves the dimensional stability of wood. Thus, a combination of complexation and hydrophobization is expected to enhance the efficiency of copper-based biocides. In this study, hydrophobic hybrid silica gel containing copper amine complexes (MACu) was prepared through an in situ sol-gel process in wood using methyltriethoxysilane (MTES), 3-amino-propyltriethoxysilane (APTES), and copper chloride. The resistance to growth of molds for MACu modified wood (Populus tomentosa) was measured according to ASTM D3273-16. A leaching resistance test was carried out in accordance with AWPA E11-16. The results showed that only Aspergillus niger covered the surface of untreated wood blocks and no mold grew on the MACu surface even after the leaching test. MACu xerogel and MACu wood were further characterized by SEM-EDS, FTIR, and XPS. A possible schematic diagram of the reaction mechanism was proposed to explain the high-efficiency anti-mold performance of MACu wood.

ChemInform Abstract: The Reductive and Oxidative Half-Reactions and the Role of Copper Ions in Plant and Mammalian Copper-Amine Oxidases.

ChemInform ◽  
2001 ◽  
Vol 32 (11) ◽  
pp. no-no
Author(s):  
Alessandra Padiglia ◽  
Rosaria Medda ◽  
Andrea Bellelli ◽  
Enzo Agostinelli ◽  
Laura Morpurgo ◽  
...  
Keyword(s):  
Copper Ions ◽  
Amine Oxidases ◽  
Copper Amine Oxidases ◽  
Copper Amine

Polarography of Copper Amine Complexes at the Dropping Copper Amalgam Electrode

1962 ◽  
Vol 84 (4) ◽  
pp. 505-513 ◽  
Author(s):  
Orien E. Schupp ◽  
Tawfiq. Youness ◽  
James I. Watters
Keyword(s):  
Amine Complexes ◽  
Amalgam Electrode ◽  
Copper Amine

The Reductive and Oxidative Half-Reactions and the Role of Copper Ions in Plant and Mammalian Copper−Amine Oxidases

2001 ◽  
Vol 2001 (1) ◽  
pp. 35-42 ◽  
Author(s):  
Alessandra Padiglia ◽  
Rosaria Medda ◽  
Andrea Bellelli ◽  
Enzo Agostinelli ◽  
Laura Morpurgo ◽  
...  
Keyword(s):  
Copper Ions ◽  
Amine Oxidases ◽  
Copper Amine Oxidases ◽  
Copper Amine
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