An exact definition of total alkalinity and a procedure for the estimation of alkalinity and total inorganic carbon from titration data

1981 ◽  
Vol 28 (6) ◽  
pp. 609-623 ◽  
Author(s):  
A.G. Dickson
2018 ◽  
Vol 15 (16) ◽  
pp. 5221-5236 ◽  
Author(s):  
Thibaut Wagener ◽  
Nicolas Metzl ◽  
Mathieu Caffin ◽  
Jonathan Fin ◽  
Sandra Helias Nunige ◽  
...  

Abstract. The western tropical South Pacific was sampled along a longitudinal 4000 km transect (OUTPACE cruise, 18 February, 3 April 2015) for the measurement of carbonate parameters (total alkalinity and total inorganic carbon) between the Melanesian Archipelago (MA) and the western part of the South Pacific gyre (WGY). This paper reports this new dataset and derived properties: pH on the total scale (pHT) and the CaCO3 saturation state with respect to aragonite (Ωara). We also estimate anthropogenic carbon (CANT) distribution in the water column using the TrOCA method (Tracer combining Oxygen, inorganic Carbon and total Alkalinity). Along the OUTPACE transect a deeper penetration of CANT in the intermediate waters was observed in the MA, whereas highest CANT concentrations were detected in the subsurface waters of the WGY. By combining our OUTPACE dataset with data available in GLODAPv2 (1974–2009), temporal changes in oceanic inorganic carbon were evaluated. An increase of 1.3 to 1.6 µmol kg−1 a−1 for total inorganic carbon in the upper thermocline waters is estimated, whereas CANT increases by 1.1 to 1.2 µmol kg−1 a−1. In the MA intermediate waters (27 kg m−3 <σθ<27.2 kg m−3) an increase of 0.4 µmol kg−1 a−1 CANT is detected. Our results suggest a clear progression of ocean acidification in the western tropical South Pacific with a decrease in the oceanic pHT of up to −0.0027 a−1 and a shoaling of the saturation depth for aragonite of up to 200 m since the pre-industrial period.


2015 ◽  
Vol 6 (2) ◽  
pp. 1499-1533 ◽  
Author(s):  
E. Gemayel ◽  
A. E. R. Hassoun ◽  
M. A. Benallal ◽  
C. Goyet ◽  
P. Rivaro ◽  
...  

Abstract. A compilation of several cruises data from 1998 to 2013 was used to derive polynomial fits that estimate total alkalinity (AT) and total inorganic carbon (CT) from measurements of salinity and temperature in the Mediterranean Sea surface waters. The optimal equations were chosen based on the 10-fold cross validation results and revealed that a second and third order polynomials fit the AT and CT data respectively. The AT surface fit showed an improved root mean square error (RMSE) of ±10.6 μmol kg−1. Furthermore we present the first annual mean CT parameterization for the Mediterranean Sea surface waters with a RMSE of ±14.3 μmol kg−1. Excluding the marginal seas of the Adriatic and the Aegean, these equations can be used to estimate AT and CT in case of the lack of measurements. The seven years averages (2005–2012) mapped using the quarter degree climatologies of the World Ocean Atlas 2013 showed that in surface waters AT and CT have similar patterns with an increasing eastward gradient. The surface variability is influenced by the inflow of cold Atlantic waters through the Strait of Gibraltar and by the oligotrophic and thermohaline gradient that characterize the Mediterranean Sea. The summer-winter seasonality was also mapped and showed different patterns for AT and CT. During the winter, the AT and CT concentrations were higher in the western than in the eastern basin, primarily due to the deepening of the mixed layer and upwelling of dense waters. The opposite was observed in the summer where the eastern basin was marked by higher AT and CT concentrations than in winter. The strong evaporation that takes place in this season along with the ultra-oligotrophy of the eastern basin determines the increase of both AT and CT concentrations.


2018 ◽  
Author(s):  
Thibaut Wagener ◽  
Nicolas Metzl ◽  
Mathieu Caffin ◽  
Jonathan Fin ◽  
Sandra Helias Nunige ◽  
...  

Abstract. The western tropical South Pacific was sampled along a longitudinal 4000 km transect (OUTPACE cruise, 18 Feb., 3 Apr. 2015) for measurement of carbonates parameters (total alkalinity and total inorganic carbon) between the Melanesian Archipelago (MA) and the western part of the South Pacific gyre (WGY). This manuscript reports this new dataset and derived properties: pH on the total scale (pHT) and the CaCO3 saturation state with respect to calcite (Ωcal) and aragonite (Ωara). We also estimate anthropogenic carbon (CANT) distribution in the water column using the TrOCA method (Tracer combining Oxygen, inorganic Carbon and total Alkalinity). Along the OUTPACE transect, CANT inventories of 37–43 mol m−2 were estimated with higher CANT inventories in MA waters (due to a deeper penetration of CANT in the intermediate waters) than in the WGY waters although highest CANT concentrations were detected in the sub-surface waters of WGY. By combining our OUTPACE dataset with data available in GLODAPv2 (1974–2009), temporal changes in oceanic inorganic carbon were evaluated. An increase of 1.3 to 1.6 µmol kg−1 a−1 for total inorganic carbon in the upper thermocline waters is estimated whereas CANT increases of 1.1 to 1.2 µmol kg−1 a−1. In the MA intermediate waters (27 kg m−3 < σθ < 27.2 kg m−3) an increase of 0.4 µmol kg−1 a−1 of CANT is detected. Our results suggest a clear progression of ocean acidification in the western tropical South Pacific with a decrease of the oceanic pH of up to −0.0027 a−1 and a shoaling of the saturation depth for aragonite of up to 200 m since the pre-industrial period.


2003 ◽  
Vol 11 (2) ◽  
pp. 169-206 ◽  
Author(s):  
Riccardo Poli ◽  
Nicholas Freitag McPhee

This paper is the second part of a two-part paper which introduces a general schema theory for genetic programming (GP) with subtree-swapping crossover (Part I (Poli and McPhee, 2003)). Like other recent GP schema theory results, the theory gives an exact formulation (rather than a lower bound) for the expected number of instances of a schema at the next generation. The theory is based on a Cartesian node reference system, introduced in Part I, and on the notion of a variable-arity hyperschema, introduced here, which generalises previous definitions of a schema. The theory includes two main theorems describing the propagation of GP schemata: a microscopic and a macroscopic schema theorem. The microscopic version is applicable to crossover operators which replace a subtree in one parent with a subtree from the other parent to produce the offspring. Therefore, this theorem is applicable to Koza's GP crossover with and without uniform selection of the crossover points, as well as one-point crossover, size-fair crossover, strongly-typed GP crossover, context-preserving crossover and many others. The macroscopic version is applicable to crossover operators in which the probability of selecting any two crossover points in the parents depends only on the parents' size and shape. In the paper we provide examples, we show how the theory can be specialised to specific crossover operators and we illustrate how it can be used to derive other general results. These include an exact definition of effective fitness and a size-evolution equation for GP with subtree-swapping crossover.


1983 ◽  
Vol 16 (2-4) ◽  
pp. 245-253
Author(s):  
Peter Berner ◽  
Christian Simhandl

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