The influence of thermal history on the mechanical properties of poly(ether ether ketone) matrix composite materials

1993 ◽  
Vol 48 (1-4) ◽  
pp. 185-190 ◽  
Author(s):  
Alexander Tregub ◽  
Hannah Harel ◽  
Gad Marom ◽  
Claudio Migliaresi
Carbon ◽  
2011 ◽  
Vol 49 (8) ◽  
pp. 2817-2833 ◽  
Author(s):  
Ana M. Díez-Pascual ◽  
Behnam Ashrafi ◽  
Mohammed Naffakh ◽  
José M. González-Domínguez ◽  
Andrew Johnston ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4475
Author(s):  
Yin Wu ◽  
Yi Cao ◽  
Ying Wu ◽  
Dichen Li

Nuclear energy provides enduring power to space vehicles, but special attention should be paid to radiation shielding during the development and use of nuclear energy systems. In this paper, novel composite materials containing poly-ether-ether-ketone (PEEK) as a substrate and different tungsten contents as a reinforcing agent were developed and tested as shielding for gamma-ray radiation. Shielding test bodies were quickly processed by fused deposition modeling (FDM) 3D printing, and their mechanical, shielding properties of composite materials were evaluated. The results revealed shielding materials with excellent mechanical properties which can further be improved by heat treatment. Under 0.45 MPa load, the heat deflection temperature of PEEK/tungsten (metal) composites was significantly lower than that of PEEK/boron carbide (non-metal) composites. The new shielding materials also demonstrated better shielding of low-energy 137Cs than high-energy 60Co. The gamma-ray shielding rates of test pieces shielding materials made of the same thickness changed exponentially with the tungsten content present in the composite materials. More tungsten led to a better shielding effect. At the same tungsten content, the gamma-ray shielding effect showed a proportional relationship with the thickness of the shielding test bodies, in which thicker test bodies induced better shielding effects. In sum, the integration of 3D printing in the mechanical design and manufacturing of shielding bodies is an effective and promising way for quick processing when considering diverse rays and complex environments. Lighter shielding bodies, at lower costs, can be achieved by structural design in limited space to maximize the material utilization rate and reduce waste.


2019 ◽  
Vol 32 (1) ◽  
pp. 103-115 ◽  
Author(s):  
Syarifah Noor Syakiylla Sayed Daud ◽  
Muhammad Noorul Anam Mohd Norddin ◽  
Juhana Jaafar ◽  
Rubita Sudirman

Sulfonated poly(ether ether ketone) (sPEEK) membrane is a promising proton-conducting membrane for fuel cell. However, the performance and lifetime of sPEEK membrane depend on the degree of sulfonation (DS). High DS of sPEEK increases the performance, but the mechanical properties could deteriorate progressively which affect its lifetime. Thus, this study investigated the effect of adding polyvinylidene fluoride (PVDF) into high DS (80%) of sPEEK through solution blending method toward its physicochemical properties and morphology structures. The PVDF concentration was varied to 5, 10, 15, and 20 wt% relative to the sPEEK content. The existence of hydrophobic PVDF in 80% sPEEK improved the mechanical properties where the water uptake and swelling degree of membrane decreased, whereas the tensile strength increased. The sPEEK/PVDF 15 exhibited the highest proton conductivity (46.23 mS cm−1) at 80°C. Incorporating PVDF into high DS of sPEEK enhanced the mechanical properties which can be used as a proton-conducting membrane for fuel cell that may improve the performance and prolong the lifetime of the cell.


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