Kinetic studies on ph dependent oxidase vs. oxygenase mechanism for Ru(III)-EDTA catalyzed oxidation of allyl alcohol by molecular oxygen in aqueous acidic medium

1989 ◽  
Vol 50 (1) ◽  
pp. 45-53 ◽  
Author(s):  
M.M.Taqui Khan ◽  
A.Prakash Rao ◽  
R.S. Shukla
Keyword(s):  
Molecular Oxygen ◽  
Allyl Alcohol ◽  
Acidic Medium ◽  
Kinetic Studies ◽  
Ph Dependent ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

Kinetics and Mechanism of Ru(III)-Catalyzed Oxidation of Paracetamol by Chloramine-T in Aqueous Acidic Medium

2009 ◽  
Vol 132 (1-2) ◽  
pp. 285-291 ◽  
Author(s):  
Ajaya Kumar Singh ◽  
Reena Negi ◽  
Bhawana Jain ◽  
Yokraj Katre ◽  
Surya P. Singh ◽  
...  
Keyword(s):  
Acidic Medium ◽  
Kinetics And Mechanism ◽  
Chloramine T ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

Kinetics of iridium(III) catalyzed oxidation of benzaldehyde and p-nitrobenzaldehyde by cerium(IV) in aqueous acidic medium

2008 ◽  
Vol 33 (6) ◽  
pp. 791-795 ◽  
Author(s):  
Praveen K. Tandon ◽  
Manisha Purwar ◽  
Priy B. Dwivedi ◽  
Manish Srivastava
Keyword(s):  
Acidic Medium ◽  
Kinetics Of ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

scholarly journals Kinetics and Mechanism of the Oxidation of Lactic Acid and Mandelic Acid by Pyridinium Chlorochromate in Aqueous Acidic Medium

2009 ◽  
Vol 6 (1) ◽  
pp. 273-280
Author(s):  
Sapana Jain ◽  
B. L. Hiran ◽  
C. V. Bhatt
Keyword(s):  
Lactic Acid ◽  
Free Radical ◽  
Reaction Mechanism ◽  
Acidic Medium ◽  
Mandelic Acid ◽  
Reaction Rate ◽  
Kinetic Studies ◽  
Pyridinium Chlorochromate ◽  
First Order ◽  
Aqueous Acidic Medium

Pyridinium chlorochromate (PCC) act as two electron oxidant in kinetic studies of the oxidation of lactic and mandelic acid in acidic medium. The influence of several factors such as acidity, salts, solvent composition and temperature on the reaction rate has been studied. The reaction shows first order dependence with respect to [PCC] and [H+]. The various thermodynamic parameters have been evaluated. Products as oxoacids and absence of free radical were confirmed. Suitable reaction mechanism has been proposed.

Iridium(III) catalyzed oxidation of toluene and ethyl benzene by cerium(IV) in aqueous acidic medium

2009 ◽  
Vol 304 (1-2) ◽  
pp. 101-106 ◽  
Author(s):  
Praveen K. Tandon ◽  
Manish Srivastava ◽  
Santosh Kumar ◽  
Satpal Singh
Keyword(s):  
Acidic Medium ◽  
Ethyl Benzene ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium
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