Electron spin resonance spectra of solvated alkali metal atoms in frozen solutions of sodium, potassium, rubidium, and caesium in hexamethylphosphoramide

1978 ◽  
Vol 13 (2) ◽  
pp. 123-169 ◽  
Author(s):  
Ron Catterall ◽  
Peter P. Edwards
Keyword(s):  
Electron Spin Resonance ◽  
Alkali Metal ◽  
Electron Spin ◽  
Sodium Potassium ◽  
Metal Atoms ◽  
Spin Resonance ◽  
Frozen Solutions

Electron spin resonance spectra of aquated alkali metal atoms

1982 ◽  
pp. 604 ◽  
Author(s):  
Peter J. Baugh ◽  
Ron Catterall ◽  
William S. Glaunsinger ◽  
Paul B. Williams
Keyword(s):  
Electron Spin Resonance ◽  
Alkali Metal ◽  
Electron Spin ◽  
Metal Atoms ◽  
Spin Resonance

Correlation of optical and electron spin resonance spectra for alkali metal solutions in ethylamine and tetrahydrofuran

1976 ◽  
Vol 54 (19) ◽  
pp. 3110-3113 ◽  
Author(s):  
R. Catterall ◽  
J. Slater ◽  
W. A. Seddon ◽  
J. W. Fletcher
Keyword(s):  
Electron Spin Resonance ◽  
Optical Absorption ◽  
Alkali Metal ◽  
Electron Spin ◽  
Hyperfine Splitting ◽  
Pulse Radiolysis ◽  
Optical Absorption Spectra ◽  
Monomeric Species ◽  
Spin Resonance ◽  
Sodium Tetraphenylboron

The band maxima of transient optical absorption spectra observed by pulse radiolysis in ethylamine (EA)/tetrahydrofuran (THF) mixtures containing sodium tetraphenylboron are correlated with electron spin resonance (esr) hyperfine splitting constants obtained in potassium/EA/THF solutions. The data suggest that the optical spectra can be attributed to the same 'monomeric' species as observed by esr in alkali metal solutions.

Equilibria of 3-Pyridylmethanol with Copper(II). A Comparative Electron Spin Resonance Study by the Decomposition of Spectra in Liquid and Frozen Solutions

2008 ◽  
Vol 112 (41) ◽  
pp. 10280-10286 ◽  
Author(s):  
Rastislav Šípoš ◽  
Terézia Szabó-Plánka ◽  
Antal Rockenbauer ◽  
Nóra Veronika Nagy ◽  
Jozef Šima ◽  
...  
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Electron Spin Resonance Study ◽  
Spin Resonance ◽  
Frozen Solutions ◽  
Comparative Electron ◽  
Spin Resonance Study

Synthesis and electron spin resonance studies of a Co(II) complex with a tetradentate macrocyclic Schiff base ligand

1977 ◽  
Vol 55 (1) ◽  
pp. 70-75 ◽  
Author(s):  
Amikam Reuveni ◽  
Vincenzo Malatesta ◽  
Bruce R. McGarvey
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Ground State ◽  
Molar Ratio ◽  
Lewis Bases ◽  
Spin Resonance ◽  
Frozen Solutions ◽  
Hamiltonian Parameters ◽  
Simulation Of Spectra ◽  
Macrocyclic Schiff Base

The synthesis, physical properties, and electron spin resonance of frozen solutions of CoTAAB(NO3)2 (TAAB = tetrabenzo[b,f,j,n] [1,5,9,13]tetraazacyclohexadecine) are reported. The spin Hamiltonian parameters were elucidated by simulation of spectra assuming axial g and 59Co hyperfine tensors and including nuclear quadrupole and Zeeman contributions. Electron spin resonance spectra in solvents such as methanol, acetone, and dimethylformamide are typical for a low spin complex (S = 1/2) and are nearly identical with [Formula: see text] and [Formula: see text]. In pyridine and quinoline a complex with a molar ratio solvent/ligand of 1:1 is formed with the solvent which gives [Formula: see text]and [Formula: see text] much closer to [Formula: see text]. In strong Lewis bases, such as piperidine, a 2:1 complex is formed and no esr signal is found. Evidence is presented to show that these 2:1 complexes with strong Lewis bases are S = 1/2 complexes with a low lying S = 3/2 state that is partially populated at room temperatures. This behaviour is accounted for in terms of a theory derived for a 2A1 ground state with a low lying quartet state which could become the ground state in strong basic solvents.

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