Electrical conductivity and defect structure of lanthanum-doped (U,Pu)O2±x

1994 ◽  
Vol 213-214 ◽  
pp. 378-380 ◽  
Author(s):  
Toshihide Tsuji ◽  
Keiji Naito ◽  
Toshiyuki Yamashita ◽  
Takeo Fujino
1989 ◽  
Vol 169 ◽  
pp. 329-335 ◽  
Author(s):  
Keiji Naito ◽  
Toshihide Tsuji ◽  
Takeo Fujino ◽  
Toshiyuki Yamashita

1986 ◽  
Vol 47 (2) ◽  
pp. 117-120 ◽  
Author(s):  
Jae Shi Choi ◽  
Keu Hong Kim ◽  
Won Yang Chung

2000 ◽  
Vol 68 (6) ◽  
pp. 507-514 ◽  
Author(s):  
Hideki KANAI ◽  
Takuya HASHIMOTO ◽  
Hiroaki TAGAWA ◽  
Junichiro MIZUSAKI

1994 ◽  
Vol 369 ◽  
Author(s):  
Yang Du ◽  
A.S. Nowick

AbstractWe have investigated the defect structure and protonic transport properties of nonstoichiometric complex perovskite-type compounds of the type A3B'1+xNb2-xO9-δ. where A and B' are both divalent ions. Protons are incorporated by treatment in H2O vapor and their presence is manifested by the appearance of an OH band in the IR spectra, as well as by the large increase in electrical conductivity to produce excellent protonic conductors, with lower activation energies. A non-classical isotope effect, in which the Arrhenius plots for D+ and H+ cross over, can be explained by a modification of the classical ART hopping theory.


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