scholarly journals The Effect of Defect Structure on Electrical Conductivity and Thermoelectric Power of La2-xSrxCuO4-δ at High Temperatures

2000 ◽  
Vol 68 (6) ◽  
pp. 507-514 ◽  
Author(s):  
Hideki KANAI ◽  
Takuya HASHIMOTO ◽  
Hiroaki TAGAWA ◽  
Junichiro MIZUSAKI
1992 ◽  
Vol 293 ◽  
Author(s):  
M.A. Spears ◽  
H.L. Tuller

AbstractWe have investigated ruthenium doped gadolinium titanate, Gd2(RuxTi1-x)2O7-δ with 0 ≤ x ≤ 0.2, to determine the role of variable valent Ru in influencing the defect structure and transport properties of the pyrochlore host. We have developed a defect chemical model to interpret electrical conductivity, thermoelectric power, and thermogravimetry data. We have found that Ru acts as an acceptor compensated in large part by oxygen vacancies, resulting in enhanced ionic conduction at low values of x. For larger values (x ≈ 0.05), electronic conductivity predominates which we attribute to electron migration by hopping through a Ru-derived defect band.


1987 ◽  
Vol 17 (6) ◽  
pp. 567-576 ◽  
Author(s):  
F. Gesmundo ◽  
O. Paladino ◽  
V. Buscaglia ◽  
G. Petot-Ervas

Author(s):  
Jan Mock ◽  
Benjamin Klingebiel ◽  
Florian Köhler ◽  
Maurice Nuys ◽  
Jan Flohre ◽  
...  

2017 ◽  
Vol 46 (18) ◽  
pp. 5872-5879 ◽  
Author(s):  
Mandvi Saxena ◽  
Tanmoy Maiti

Increasing electrical conductivity in oxides, which are inherently insulators, can be a potential route in developing oxide-based thermoelectric power generators with higher energy conversion efficiency.


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